SURFACE-STRUCTURE AND REACTIVITY OF AROMATIC-MOLECULES - CAN WE TRACK DOWN TRENDS IN THE PERIODIC-TABLE

被引：59
作者：
NETZER, FP
机构：
[1] Institut für Physikalische Chemie, Universität Innsbruck
来源：
LANGMUIR | 1991年 / 7卷 / 11期
关键词：
D O I：
10.1021/la00059a025
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The adsorption characteristics of benzene on transition-metal surfaces as a prototype molecule for aromatic systems are investigated to search for trends across the periodic table. Data on adsorbate structure and orientation, intramolecular structure, and molecular stability are collected and discussed comparatively. The strength of benzene-metal surface interactions increases in going from the right to the left in the periodic table and thus follows the general trend of chemical reactivity. However, the second period seems to behave exceptionally, in that remarkable molecular stability is encountered on these surfaces. The details of the surface chemical bond of aromatic molecules are still poorly understood, and the need for more rigorous theoretical treatment is emphasized.
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页码：2544 / 2547
页数：4
相关论文
共 46 条
[1]   ADSORPTION STATES OF BENZENE AND TOLUENE ON PT(111) - A VIBRATIONAL EELS, DELTA-PHI, AES AND TDS STUDY [J].
ABON, M ;
BERTOLINI, JC ;
BILLY, J ;
MASSARDIER, J ;
TARDY, B .
SURFACE SCIENCE, 1985, 162 (1-3) :395-401
[2]   THERMAL-DESORPTION AND PHOTOELECTRON-SPECTROSCOPY STUDIES OF BENZENE ADSORBED ON POLYCRYSTALLINE RHENIUM [J].
ALNOT, M ;
DUCROS, R ;
EHRHARDT, JJ ;
TATARENKO, S .
APPLICATIONS OF SURFACE SCIENCE, 1982, 14 (01) :114-121
[3]  
ANDERSEN OK, 1984, ELECTRONIC STRUCTURE
[4]   STRUCTURE AND ELECTRONIC FACTORS IN BENZENE COORDINATION TO CR(CO)3 AND TO CLUSTER-MODELS OF NI, PT, AND AG(111) SURFACES [J].
ANDERSON, AB ;
MCDEVITT, MR ;
URBACH, FL .
SURFACE SCIENCE, 1984, 146 (01) :80-92
[5]  
[Anonymous], 1988, SOLIDS SURFACES CHEM
[6]  
BERTEL E, 1986, SURF SCI, V172, pL515, DOI 10.1016/0039-6028(86)90578-9
[7]   BENZENE ADSORPTION ON NICKEL (100) AND (111) FACES STUDIED BY LEED AND HIGH-RESOLUTION ELECTRON-ENERGY LOSS SPECTROSCOPY [J].
BERTOLINI, JC ;
DALMAIIMELIK, G ;
ROUSSEAU, J .
SURFACE SCIENCE, 1977, 67 (02) :478-488
[8]   VIBRATIONAL ELECTRON-ENERGY LOSS SPECTRA OF BENZENE CHEMISORBED ON THE (111) AND (100) NICKEL FACES [J].
BERTOLINI, JC ;
ROUSSEAU, J .
SURFACE SCIENCE, 1979, 89 (1-3) :467-476
[9]   THE ADSORPTION AND DECOMPOSITION OF BENZENE ON NI(100) AND THE EFFECTS OF PREADSORBED C, O, H, AND CO [J].
BLASS, PM ;
AKHTER, S ;
WHITE, JM .
SURFACE SCIENCE, 1987, 191 (03) :406-424
[10]   THE ELECTRONIC-STRUCTURE OF BENZENE ADSORBED ON AG(111) STUDIED BY ANGLE RESOLVED PHOTOEMISSION [J].
DUDDE, R ;
FRANK, KH ;
KOCH, EE .
SURFACE SCIENCE, 1990, 225 (03) :267-272
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