PRODUCTS OF REACTIONS OF MO AND ZR COMPOUNDS IN MOLTEN NITRATE

被引：13

作者：

AFANASIEV, P ^{[1
]}

GEANTET, C ^{[1
]}

KERRIDGE, DH ^{[1
]}

机构：

[1] UNIV SOUTHAMPTON,DEPT ENGN MATH,SOUTHAMPTON SO9 5NH,HANTS,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 02期

关键词：

D O I：

10.1039/jm9950500347

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reactions of Mo and Zr compounds in molten nitrate media have been studied. It has been shown that an interaction between Zr-IV and Mo-VI species occurs in nitrate melts, leading to the formation of high-surface-area mixed-oxide solids containing dispersed molybdate species grafted onto small zirconia particles. The physico-chemical properties of the products were studied vs. reaction temperature, nature of the alkali-metal cation and Mo reactant. The reaction temperature was of primary importance in determining the composition and structure of the product. At 30 degrees C, amorphous zirconia with randomly distributed monomolybdate species was formed, whereas at 500 degrees C crystalline ZrO2 superficially modified by polymolybdate was obtained. The alkali-metal cation influenced the amount of Mo in the solid and its dispersion.

引用

页码：347 / 352

页数：6

共 41 条

[11] CHARACTERISTICS AND SINTERING BEHAVIOR OF 3 MOL PERCENT Y2O3-ZRO2 POWDERS SYNTHESIZED BY REACTION IN MOLTEN-SALTS [J].

DESCEMOND, M ;

BRODHAG, C ;

THEVENOT, F ;

DURAND, B ;

JEBROUNI, M ;

ROUBIN, M .

JOURNAL OF MATERIALS SCIENCE, 1993, 28 (09) :2283-2288

[12] SOLUBILITY AND DETECTION (DOWN TO 30 PPB) OF OXYGEN IN MOLTEN ALKALI NITRATES [J].

DESIMONI, E ;

ZAMBONIN, PG ;

PANICCIA, F .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1972, 38 (02) :373-&

[13]

DURAND B, 1991, MATER SCI FORUM, V73, P663, DOI 10.4028/www.scientific.net/MSF.73-75.663

[14] MOLTEN LITHIUM NITRATE-POTASSIUM NITRATE EUTECTIC - SOME REACTIONS OF COPPER(II) AND OF METALLIC SILVER [J].

FROUZANFAR, H ;

KERRIDGE, DH .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1979, 41 (02) :181-184

[15] MOLTEN NITRATE EUTECTICS - THE REACTION OF 4 LANTHANIDE CHLORIDES [J].

HABBOUSH, DA ;

KERRIDGE, DH ;

TARIQ, SA .

THERMOCHIMICA ACTA, 1983, 65 (01) :53-60

[16]

HABBOUSH DA, 1974, THERMOCHIM ACTA, V10, P187

[17] Molten salt preparation of stabilized zirconia catalysts: characterization and catalytic properties [J].

Hamon, D. ;

Vrinat, M. ;

Breysse, M. ;

Durand, B. ;

Jebrouni, M. ;

Roubin, M. ;

Magnoux, P. ;

des Courieres, T. .

CATALYSIS TODAY, 1991, 10 (04) :613-627

[18]

HAMON D, 1993, EUR J SOL STATE INOR, V30, P713

[19]

HAMON D, 1991, B SOC CHIM BELG, V100, P933

[20]

IANIBELLO A, 1984, J CHEM SOC F1, V80, P2209

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