INVESTIGATION OF THE AQUEOUS LITHIUM AND MAGNESIUM HALIDE-SYSTEMS

被引：52

作者：

CHRISTOV, C ^{[1
]}

BALAREW, C ^{[1
]}

PETRENKO, S ^{[1
]}

VALYASHKO, V ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,NS KURNAKOV INST GEN & INORGAN CHEM,117907 MOSCOW,RUSSIA

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1994年 / 23卷 / 05期

关键词：

SOLUBILITY DIAGRAM; DOUBLE SALTS; PITZERS MODEL; BROMOCARNALLITE; CARNALLITE;

D O I：

10.1007/BF00972747

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The solubilities of the system LiBr-MgBr2-H2O have been investigated at 25-degrees-C and 50-degrees-C. It is established that the system is of a simple eutonic type. Pitzer's model is used for calculating the thermodynamic functions needed for plotting the solubility isotherms of the systems LiX-MgX2-H2O (X = Cl, Br) at 25-degrees-C. According to calculations made, the Gibbs energy of formation of LiCl.MgCl2.7H2O from simple salts is DELTA(r)G(m)o = -2.01 kJ-mol-1, while the value DELTA(f)G(m)o = -2748 kJ-mol-1 corresponds to formation from the elements.

引用

页码：595 / 604

页数：10

共 20 条

[1]

Baimuradov R, 1969, IZV AKAD NAUK FTKGN, V2, P87

[2] THERMODYNAMICS OF FORMATION OF CARNALLITE TYPE DOUBLE SALTS [J].

BALAREW, C ;

CHRISTOV, C ;

VALYASHKO, V ;

PETRENKO, S .

JOURNAL OF SOLUTION CHEMISTRY, 1993, 22 (02) :173-181

[3]

Balarew C, 1970, COMM DEP CHEM BAS, V3, P637

[4]

BILTZ W, 1911, Z ANORG CHEM, V71, P169

[5]

BLIDIN V, 1947, J GENERAL CHEM, V7, P1593

[6] THE SYSTEM MAGNESIUM BROMIDE, AMMONIUM BROMIDE AND WATER AT 25-DEGREES [J].

CAMPBELL, JA ;

MARSH, FL .

JOURNAL OF PHYSICAL CHEMISTRY, 1959, 63 (02) :316-317

[7] CRYSTAL-CHEMISTRY OF MX.MGX2.6H2O TYPE COMPOUNDS [J].

EMONS, HH ;

BRAND, P ;

POHL, T ;

KOHNKE, K .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 563 (08) :180-184

[8] SOLID-LIQUID PHASE-EQUILIBRIA IN THE SYSTEM KCL-MGCL2-H2O AT ELEVATED-TEMPERATURES .3. ISOTHERMS AT 160-DEGREES-C, 170-DEGREES-C, AND 180-DEGREES-C [J].

FANGHANEL, T ;

EMONS, HH ;

KOHNKE, K .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1989, 576 (09) :99-107

[9] THERMODYNAMICS OF PHASE-EQUILIBRIA OF AQUEOUS (LITHIUM-SULFATE + CESIUM-SULFATE), (SODIUM-SULFATE + CESIUM-SULFATE), AND (POTASSIUM-SULFATE + CESIUM-SULFATE) AT 298.15-K USING PITZER MODEL [J].

FILIPPOV, VK ;

KALINKIN, AM ;

VASIN, SK .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1987, 19 (02) :185-193

[10]

HEIKS J, 1954, J AM CHEM SOC, V76, P2590

← 1 2 →