ORGANIC-SOLID STATE REACTIONS .1. CATALYTIC-HYDROGENATION OF SOLID 4-TERT-BUTYLPHENOL - ACTIVITY AND SELECTIVITY OF SUPPORTED CATALYSTS, MECHANISM OF SOLID-STATE HYDROGENATION

被引：0
|
作者：
SABRA, F
LAMARTINE, R
机构：
来源：
NEW JOURNAL OF CHEMISTRY | 1992年 / 16卷 / 11期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The solid state hydrogenation of 4-tert-butylphenol has been studied in the presence of various supported catalysts. The reaction has been carried out under mild conditions; at room temperature and under one bar hydrogen pressure. It is shown that this hydrogenation is a real organic solid state reaction and that reactivity and selectivity are dependent on the catalyst used. Taking into account electronic conduction and transfer of mobile hydrogen species, a mechanism is proposed to explain the course of the reaction and the isomeric distribution of cis and trans alcohols.
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页码：1043 / 1048
页数：6
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