ORGANIC-SOLID STATE REACTIONS .1. CATALYTIC-HYDROGENATION OF SOLID 4-TERT-BUTYLPHENOL - ACTIVITY AND SELECTIVITY OF SUPPORTED CATALYSTS, MECHANISM OF SOLID-STATE HYDROGENATION

被引：0
|
作者：
SABRA, F
LAMARTINE, R
机构：
来源：
NEW JOURNAL OF CHEMISTRY | 1992年 / 16卷 / 11期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The solid state hydrogenation of 4-tert-butylphenol has been studied in the presence of various supported catalysts. The reaction has been carried out under mild conditions; at room temperature and under one bar hydrogen pressure. It is shown that this hydrogenation is a real organic solid state reaction and that reactivity and selectivity are dependent on the catalyst used. Taking into account electronic conduction and transfer of mobile hydrogen species, a mechanism is proposed to explain the course of the reaction and the isomeric distribution of cis and trans alcohols.
引用
收藏
页码：1043 / 1048
页数：6
相关论文
共 50 条
  • [21] SURFACE SOLID-STATE INTERACTIONS IN COPPER-NICKEL-CEMENT CATALYSTS FOR HYDROGENATION OF OXYGEN
    DULOV, AA
    ABRAMOVA, LA
    STASENKO, EM
    EFREMOV, VN
    TESAKOVA, GM
    GOLOSMAN, EZ
    YAKERSON, VI
    RUSSIAN CHEMICAL BULLETIN, 1994, 43 (09) : 1471 - 1474
  • [22] Solid-state hydrogenation/hydrogenolysis of high-rank bituminous coals with gaseous catalysts
    Haenel, Matthias W.
    Richter, Udo-Burckhard
    Rufinska, Anna
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237 : 861 - 861
  • [23] Catalytic activity of a zeolite disc synthesized through solid-state reactions
    Kiricsi, I
    Shimizu, S
    Kiyozumi, Y
    Toba, M
    Niwa, S
    Mizukami, F
    MICROPOROUS AND MESOPOROUS MATERIALS, 1998, 21 (4-6) : 453 - 459
  • [24] Catalytic activity of a zeolite disc synthesized through solid-state reactions
    Jozsef Attila Univ, Szeged, Hungary
    Microporous Mesoporous Mater, 4-6 (453-459):
  • [25] Solid-phase catalytic reactions of tritium with carbohydrates: 1. Influence of temperature, catalysts, and solid phase composition on solid-phase catalytic hydrogenation of D-ribose with tritium
    Baitov A.A.
    Sidorov G.V.
    Myasoedov N.F.
    Radiochemistry, 2005, 47 (2) : 201 - 203
  • [26] Influence of electron state of rhodium in supported bimetallic catalysts on their activity and selectivity in reactions of carbon monoxide hydrogenation
    Trypolsky, AI
    Pavlenko, MV
    Zakumbaeva, GD
    TEORETICHESKAYA I EKSPERIMENTALNAYA KHIMIYA, 1997, 33 (04): : 199 - 218
  • [27] Solid-State Synthesis of Metal Nanoparticles Supported on Cellulose Nanocrystals and Their Catalytic Activity
    Eisa, Wael H.
    Abdelgawad, Abdelrahman M.
    Rojas, Orlando J.
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (03): : 3974 - 3983
  • [28] Catalytic hydrogenation and dehydrogenation over solid-state rhenium sulfide clusters with an octahedral metal framework
    Kamiguchi, Satoshi
    Nagashima, Sayoko
    Chihara, Teiji
    CHEMISTRY LETTERS, 2007, 36 (11) : 1340 - 1341
  • [29] Solid-state NaBH4 composites for hydrogen generation: Catalytic activity of nickel and cobalt catalysts
    Netskina, O. V.
    Tayban, E. S.
    Rogov, V. A.
    Ozerova, A. M.
    Mukha, S. A.
    Simagina, V. I.
    Komova, O. V.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (07) : 5459 - 5471
  • [30] STRUCTURAL STUDIES ON COAL USING SOLID-STATE NMR AND MASS-SPECTROMETRY .2. CATALYTIC-HYDROGENATION OF COAL UNDER MILD CONDITIONS
    PRASAD, JV
    DAS, KG
    DEREPPE, JM
    FUEL, 1991, 70 (02) : 189 - 193
12345