FROM A MOLECULAR VIEW ON SOLIDS TO MOLECULES IN SOLIDS

被引:17
作者
SIMON, A
机构
[1] Max-Planck-Institut für Festkörperforschung
关键词
SOLIDS; MOLECULES; METAL-RICH COMPOUNDS; SUPERCONDUCTIVITY;
D O I
10.1016/0925-8388(95)01681-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structural chemistry of metal-rich compounds formed by metals in groups 1 to 6 is largely based on discrete and condensed clusters. Interstitial atoms play an important role. Structure-property relations are addressed, particularly concerning the interplay of metal-metal bonds and localized magnetic moments as well as superconductivity. Experimental techniques developed for these investigations have been frequently used for low temperature structure research on molecular crystals which is illustrated for HBr, N2O3, NOxCl (x = 1, 2, 3), and P-4.
引用
收藏
页码:158 / 174
页数:17
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