AN ABINITIO MOLECULAR-ORBITAL STUDY OF THE INSERTIONS OF DIFLUOROCARBENE OR FLUOROCARBENE INTO ETHENE

被引：0
|
作者：
WONG, CK [1 ]
CHEUNG, CY [1 ]
MA, NL [1 ]
LI, WK [1 ]
机构：
[1] CHINESE UNIV HONG KONG, DEPT CHEM, SHA TIN, HONG KONG
来源：
JOURNAL OF CHEMICAL RESEARCH | 1993年 / 01期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Inclusion of correlation effects in ab initio MO calculations yields an activation energy for the insertion of difluorocarbene into ethene that is in excellent agreement with the experimental result; a similar calculation predicts that the insertion of fluorocarbene into ethene requires no activation energy.
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页码：32 / 33
页数：2
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