A CONCISE SYNTHESIS OF (-)-CONDURITOL-F FROM L-QUEBRACHITOL VIA ALCL3-NORMAL-BU4NI MEDIATED DEMETHYLATION

被引：43
作者：
AKIYAMA, T
SHIMA, H
OZAKI, S
机构：
[1] Department of Applied Chemistry, Faculty of Engineering, Ehime University, Matsuyama, 790, Bunkyo-cho
来源：
TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期
关键词：
(-)-CONDURITOL-F; (+)-CONDURITOL-B; L-QUEBRACHITOL; DEMETHYLATION; ALCL3;
D O I：
10.1016/0040-4039(91)80092-K
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
(-)-Conduritol F was prepared starting from naturally occurring cyclitol, L-quebrachitol, in 5 steps via AlCl3-Bu4NI mediated chemoselective demethylation of the methyl ether. A preparation of (+)-conduritol B was also described.
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页码：5593 / 5596
页数：4
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