SYNTHESIS, STEREOCHEMICAL ANALYSIS, AND LIGAND-TRANSFORMATION REACTIONS OF NEW CLASSES OF BICAPPED TRICOBALT CLUSTERS, [CO3(ETA-5-C5H5-XMEX)3(MU-3-X)(MU-3-Y)]N (X = 0, 1, 5,), CONTAINING MIXED PI-ACCEPTOR X AND PI-DONOR Y CAPPING LIGANDS (X = CO, NO - Y = NSIME3, NC(O)NH2,NH) - A RATIONAL PREPARATIVE ROUTE TO NITRENE (MU-3-NH) CLUSTERS AND THE UNPRECEDENTED DIRECT EXCHANGE OF AN ISOELECTRONIC MU-3-NO+ LIGAND FOR A MU-3-CO LIGAND3

被引：43

作者：

BEDARD, RL ^{[1
]}

RAE, AD ^{[1
]}

DAHL, LF ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1986年 / 108卷 / 19期

关键词：

D O I：

10.1021/ja00279a043

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：5924 / 5932

页数：9

共 62 条

[31] ORGANOMETALLIC CHALCOGEN COMPLEXES .25. STRUCTURAL AND MAGNETIC STUDIES OF CO3(H5-C5H5)3(CO)(S), CO3(H5-C5H5)3S2, AND OXIDIZED MONOCATION, [CO3(H5-C5H5)3S2]+ - SENSITIVITY OF GEOMETRY OF A TRIANGULAR METAL CLUSTER SYSTEM TO ANTIBONDING ELECTRONS [J].

FRISCH, PD ;

DAHL, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (14) :5082-&

[32]

GLADFELTER WL, 1984, 188TH NAT M AM CHEM

[33] HETERONUCLEAR UNSATURATED DINUCLEAR AND TRI-NUCLEAR METAL-COMPLEXES - CRYSTAL-STRUCTURES OF [CORH(MU-CO)2(ETA-C5ME5)2] AND [RH2(MU-CO)2(ETA-C5ME5)2] [J].

GREEN, M ;

HANKEY, DR ;

HOWARD, JAK ;

LOUCA, P ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (14) :757-758

[34]

Hamilton W. C., 1968, HYDROGEN BONDING SOL

[35] ELECTRON-TRANSFER MECHANISM FOR A HYDRIDE-TRANSFER REACTION - EVIDENCE FOR SELECTIVE ALPHA-HYDRIDE ABSTRACTION FROM A TRANSITION-METAL ALKYL [J].

HAYES, JC ;

COOPER, NJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (20) :5570-5572

[36]

HOCK AA, 1961, ADV CHEM COORDINATIO, P640

[37]

HOWARD JAK, 1983, COMMUNICATION NOV

[38] THE 1ST NITROSYL DERIVATIVES OF HIGH NUCLEARITY CARBONYL CLUSTERS - SYNTHESIS AND X-RAY-ANALYSIS OF THE [(PH3P)2N]+ SALTS OF THE ANIONS [OS10C(CO)24(MU-2-NO)]- AND [OS10C(CO)23(NO)]- [J].

JOHNSON, BFG ;

LEWIS, J ;

NELSON, WJH ;

PUGA, J ;

BRAGA, D ;

HENRICK, K ;

MCPARTLIN, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 266 (02) :173-189

[39] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE CLUSTER CATION [OS4(MU-2-H)3(CO)12(NCME)2]+ - AN EXAMPLE OF AN UNSUPPORTED BUTTERFLY OS4 GEOMETRY [J].

JOHNSON, BFG ;

LEWIS, J ;

NELSON, WJH ;

PUGA, J ;

RAITHBY, PR ;

SCHRODER, M ;

WHITMIRE, KH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (11) :610-612

[40] STEREOCHEMICAL AND ELECTROCHEMICAL ANALYSES OF THE CYCLOPENTADIENYL AND METHYLCYCLOPENTADIENYL DINITROSYL-CAPPED TRICOBALT ANALOGS, CO3(ETA-5-C5H5-XMEX)3(MU-3-NO)2 (WHERE X = 0, 1), OF THE CLASSICAL FISCHER-PALM NI3(ETA-5-C5H5)3(MU-3-CO)2 [J].

KUBATMARTIN, KA ;

RAE, AD ;

DAHL, LF .

ORGANOMETALLICS, 1985, 4 (12) :2221-2223

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