HYDROGENOLYSIS OF DIMETHYL SUCCINATE OVER RANEY COPPER CATALYST - A CORRECTION

被引：16

作者：

THOMAS, DJ ^{[1
]}

STAMMBACH, MR ^{[1
]}

CANT, NW ^{[1
]}

WAINWRIGHT, MS ^{[1
]}

TRIMM, DL ^{[1
]}

机构：

[1] UNIV NEW S WALES,SCH CHEM ENGN & IND CHEM,POB 1,KENSINGTON,NSW 2033,AUSTRALIA

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1990年 / 29卷 / 02期

关键词：

D O I：

10.1021/ie00098a009

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Previous studies of the hydrogenolysis of dimethyl succinate over Raney copper (Kohler et al., 1987) appeared to show that 1,4-butanediol could be produced in high yields and with high selectivity. Improved thermodynamic data showed that this reaction was improbable, and the system has been reexamined. It is found that γ-butyrolactone (GBL) and tetrahydrofuran (THF) are the main products of reaction. New experimental data are presented, and the kinetics of hydrogenolysis have been examined. Succinic acid, produced by reaction of traces of water with dimethyl succinate, has been found to inhibit the reaction. © 1990, American Chemical Society. All rights reserved.

引用

页码：204 / 208

页数：5

共 4 条

[1] Dell R.M., 1953, T FARADAY SOC, V49, P159
[2] REACTION-KINETICS AND SELECTIVITY OF DIMETHYL SUCCINATE HYDROGENOLYSIS OVER COPPER-BASED CATALYSTS
KOHLER, MA
WAINWRIGHT, MS
TRIMM, DL
CANT, NW
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1987, 26 (04) : 652 - 656
[3] ZINC-PROMOTED RANEY COPPER-CATALYSTS FOR METHANOL SYNTHESIS
MARSDEN, WL
WAINWRIGHT, MS
FRIEDRICH, JB
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1980, 19 (04): : 551 - 556
[4] 1981, HDB CHEM PHYSICS

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