Material Selection for Accident Tolerant Fuel Cladding

被引:242
作者
Pint, B. A. [1 ]
Terrani, K. A. [1 ]
Yamamoto, Y. [1 ]
Snead, L. L. [1 ]
机构
[1] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
来源
METALLURGICAL AND MATERIALS TRANSACTIONS E-MATERIALS FOR ENERGY SYSTEMS | 2015年 / 2卷 / 03期
关键词
D O I
10.1007/s40553-015-0056-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Alternative cladding materials to Zr-based alloys are being investigated for accident tolerance, which can be defined as > 100X improvement (compared to Zr-based alloys) in oxidation resistance to steam or steam-H-2 environments at >= 1473 K (1200 degrees C) for short times. After reviewing a wide range of candidates, current steam oxidation testing is being conducted on Mo, MAX phases, and FeCrAl alloys. Recently reported low-mass losses for Mo in steam at 1073 K (800 degrees C) could not be reproduced. Both FeCrAl and MAX phase Ti2AlC form a protective alumina scale in steam. However, commercial Ti2AlC that was not single phase, formed a much thicker oxide at 1473 K (1200 degrees C) in steam and significant TiO2, and therefore, Ti2AlC may be challenging to form as a cladding or a coating. Alloy development for FeCrAl is seeking to maintain its steam oxidation resistance to 1748 K (1475 degrees C), while reducing its Cr content to minimize susceptibility to irradiation-assisted alpha' formation. The composition effects and critical limits to retaining protective scale formation at > 1673 K (1400 degrees C) are still being evaluated. (C) ASM International (ASM) and The Minerals, Metals & Materials Society (TMS) 2015
引用
收藏
页码:190 / 196
页数:7
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