SOLID POLYMER ELECTROLYTES BASED ON POLYETHYLENE OXIDE-SILVER THIOCYANATE

被引：46
|
作者：
SEKHON, SS
SINGH, G
AGNIHOTRY, SA
CHANDRA, S
机构：
[1] NATL PHYS LAB,NEW DELHI 110012,INDIA
[2] BANARAS HINDU UNIV,DEPT PHYS,VARANASI 221005,UTTAR PRADESH,INDIA
来源：
SOLID STATE IONICS | 1995年 / 80卷 / 1-2期
关键词：
ELECTROLYTE; POLYETHYLENE OXIDE (PEO); POLYMER; SILVER THIOCYANATE;
D O I：
10.1016/0167-2738(95)00121-L
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The polymer electrolyte films obtained by the addition of silver thiocyanate to polyethylene oxide have been investigated by complex impedance spectroscopy, X-ray diffraction, FTIR, optical microscopy and transference number measurement techniques. It has been observed that complexation takes place mainly in the amorphous region and conductivity of the order of 10(-6) S cm(-1) has been observed at room temperature. Transference number measurements show that these polymers are mainly anionic conductors. The polymer films have also been found to be sensitive to light.
引用
收藏
页码：37 / 44
页数：8
相关论文
共 50 条
  • [31] Ferroelectric materials as a ceramic filler in solid composite polyethylene oxide-based electrolytes
    Sun, HY
    Takeda, Y
    Imanishi, N
    Yamamoto, O
    Sohn, HJ
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (07) : 2462 - 2467
  • [32] Studies on New Polymeric Solid Electrolytes Based on Urea and Thiocyanate
    Wang, Zhi-Yin
    He, Yun-Hua
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 2002, 23 (12):
  • [33] Studies on new polymeric solid electrolytes based on urea and thiocyanate
    Wang, ZY
    He, YH
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (12): : 2375 - 2377
  • [34] Electrospun Li(TFSI)@Polyethylene Oxide Membranes as Solid Electrolytes
    Walke, Patrick
    Freitag, Katharina M.
    Kirchhain, Holger
    Kaiser, Matthias
    van Wuellen, Leo
    Nilges, Tom
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2018, 644 (24): : 1863 - 1874
  • [35] Transparent heat mirrors based on tungsten oxide-silver multilayer structures
    Al-Kuhaili, M. F.
    Al-Aswad, A. H.
    Durrani, S. M. A.
    Bakhtiari, I. A.
    SOLAR ENERGY, 2009, 83 (09) : 1571 - 1577
  • [36] New oligoether plasticizers for poly(ethylene oxide)-based solid polymer electrolytes
    Qiang Ma
    Amartya Chakrabarti
    Xinyi Mei
    Zheng Yue
    Hamza Dunya
    Robert Filler
    Braja K. Mandal
    Ionics, 2019, 25 : 1633 - 1643
  • [37] New oligoether plasticizers for poly(ethylene oxide)-based solid polymer electrolytes
    Ma, Qiang
    Chakrabarti, Amartya
    Mei, Xinyi
    Yue, Zheng
    Dunya, Hamza
    Filler, Robert
    Mandal, Braja K.
    IONICS, 2019, 25 (04) : 1633 - 1643
  • [38] Solid state NMR study of sodium thiocyanate/poly(ethylene oxide) electrolytes
    Bartolotta, A
    Forte, C
    Geppi, M
    Minniti, D
    Visalli, G
    SOLID STATE NUCLEAR MAGNETIC RESONANCE, 1997, 8 (04) : 231 - 239
  • [39] SOLID POLYMER ELECTROLYTES BASED ON STATISTICAL POLY (ETHYLENE OXIDE-PROPYLENE OXIDE) COPOLYMERS
    ANDRIEU, X
    FAUVARQUE, JF
    GOUX, A
    HAMAIDE, T
    MHAMDI, R
    VICEDO, T
    ELECTROCHIMICA ACTA, 1995, 40 (13-14) : 2295 - 2299
  • [40] IONOMETRIC DETERMINATION OF SILVER IN DICYANOARGENTATE THIOCYANATE ELECTROLYTES
    STULGENE, IK
    TAUTKUS, SA
    KAZLAUSKAS, RM
    PETRUKHIN, OM
    INDUSTRIAL LABORATORY, 1989, 55 (12): : 1349 - 1350
12345