SYNTHESIS AND ENANTIOMER RECOGNITION OF CROWN ETHERS CONTAINING CYCLOHEXANE-1,2-DIOL DERIVATIVES AS THE CHIRAL CENTER AND ENZYMATIC RESOLUTION OF THE CHIRAL SUBUNITS

被引：17

作者：

NAEMURA, K

MIYABE, H

SHINGAI, Y

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 04期

关键词：

D O I：

10.1039/p19910000957

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cyclohexane-1,2-diol derivatives 1 and 4 of high optical purity have been prepared by enantioselective hydrolysis of their acetates (+/-)-2 and (+/-)-5 using pig liver esterase. The enantiomer recognition behaviour of the chiral crown ethers 11, 14, 15 and 16 containing the cyclohexane-1,2-diol derivatives as a chiral subunit has also been examined.

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页码：957 / 959

页数：3

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