PLATINUM-GROUP METAL FUNCTIONALIZED PHOSPHINE COMPLEXES .1. PHOSPHINOAMIDE RUTHENIUM(II) COMPLEXES

被引：0

作者：

SATYANARAYANA, T ^{[1
]}

REDDY, KV ^{[1
]}

机构：

[1] OSMANIA UNIV,DEPT CHEM,HYDERABAD 500007,ANDHRA PRADESH,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new bifunctional phosphinoamide ligands of the type Ph2PCH2C(O)NHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized. Their ruthenium(II) complexes prepared from two different precursors, RuCl2(DMSO)4 and RuCl2(PPh3)3, are of similar composition and correspond to the formula, [RuCl(L)2(P-O)2]Cl (L = DMSO/PPh3; phosphinoamide). However, RuCl3(AsPh3)2(MeOH) reacts with the phosphinoamide to yield a reduced product of the cis-RUCl2(P-O)2 type. The ligands and complexes were characterized by mass, i.r. and n.m.r. spectroscopy. Possible stereochemistries for the complexes are proposed.

引用

页码：283 / 289

页数：7

共 54 条

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