PLATINUM-GROUP METAL FUNCTIONALIZED PHOSPHINE COMPLEXES .1. PHOSPHINOAMIDE RUTHENIUM(II) COMPLEXES

被引：0

作者：

SATYANARAYANA, T ^{[1
]}

REDDY, KV ^{[1
]}

机构：

[1] OSMANIA UNIV,DEPT CHEM,HYDERABAD 500007,ANDHRA PRADESH,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1994年 / 19卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new bifunctional phosphinoamide ligands of the type Ph2PCH2C(O)NHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized. Their ruthenium(II) complexes prepared from two different precursors, RuCl2(DMSO)4 and RuCl2(PPh3)3, are of similar composition and correspond to the formula, [RuCl(L)2(P-O)2]Cl (L = DMSO/PPh3; phosphinoamide). However, RuCl3(AsPh3)2(MeOH) reacts with the phosphinoamide to yield a reduced product of the cis-RUCl2(P-O)2 type. The ligands and complexes were characterized by mass, i.r. and n.m.r. spectroscopy. Possible stereochemistries for the complexes are proposed.

引用

页码：283 / 289

页数：7

共 54 条

[1] AUBURN MJ, 1984, J AM CHEM SOC, V106, P1314, DOI 10.1021/ja00317a024
[2] STUDIES ON THE METAL-AMIDE BOND .7. METAL-COMPLEXES OF THE FLEXIBLE N4 LIGAND N,N'-BIS(2'-PYRIDINE-CARBOXAMIDE)1,2-ETHANE
BARNES, DJ
CHAPMAN, RL
STEPHENS, FS
VAGG, RS
[J]. INORGANICA CHIMICA ACTA-ARTICLES, 1981, 51 (02): : 155 - 162
[3] Bellamy L.J, 1975, INFRARED SPECTRA COM, P231, DOI DOI 10.1007/978-94-011-6017-9_12
[4] HYDROGENATION AND COUPLING OF VINYL GROUPS IN COORDINATION SPHERE OF A DIVALENT RUTHENIUM COMPLEX FORMED BY AN OLEFINIC TERTIARY PHOSPHINE
BENNETT, MA
JOHNSON, RN
TOMKINS, IB
[J]. INORGANIC CHEMISTRY, 1975, 14 (08) : 1908 - 1915
[5] BRUNSTEIN P, 1978, J CHEM RES SYNO, P232
[6] BRUNSTEIN P, 1978, J CHEM RES MINIPRINT, P3041
[7] BRUNSTEIN P, 1981, J AM CHEM SOC, V103, P5115
[8] SYNTHESIS AND SPECTROSCOPIC AND X-RAY STRUCTURAL CHARACTERIZATION OF BIS(DIPHENYLPHOSPHINO(PHENYL)ACETYLENE)HEXACARBONYLDIIRON(O), AN ALKYNE DERIVATIVE OF IRON PENTACARBONYL
CARTY, AJ
PAIK, HN
PALENIK, GJ
[J]. INORGANIC CHEMISTRY, 1977, 16 (02) : 300 - 305
[9] SYNTHESIS AND MOLECULAR-STRUCTURE OF RU2(C5NH4NH)6(PME2PH)2, A RU RU-BONDED MOLECULE WITH 2-PYRIDINYLAMIDE LIGANDS IN 3 COORDINATION MODES AND OTHER NOVEL FEATURES
CHAKRAVARTY, AR
COTTON, FA
TOCHER, DA
[J]. INORGANIC CHEMISTRY, 1984, 23 (24) : 4030 - 4033
[10] STUDIES ON THE METAL-AMIDE BOND .1. METAL-COMPLEXES OF THE BIS-AMIDE TETRADENTATE LIGAND N,N'-BIS(2'-PYRIDINE-CARBOXAMIDE)-1,2-BENZENE
CHAPMAN, RL
VAGG, RS
[J]. INORGANICA CHIMICA ACTA, 1979, 33 (02) : 227 - 234

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