DICARBONYLGOLD(I) HEXAFLUOROURANATE(VI), AU(CO)2UF6

被引：39

作者：

ADELHELM, M

BACHER, W

HOHN, EG

JACOB, E

机构：

[1] KERNFORSCHUNGSZENTRUM KARLSRUHE GMBH,INST MIKROSTRUKT TECH,W-7500 KARLSRUHE 1,GERMANY

[2] MAN TECHNOL AG,W-8000 MUNICH,GERMANY

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 07期

关键词：

GOLD CARBONYL COMPLEXES; URANIUM HEXAFLUORIDE; GOLD(I) BIS(CARBONYL) CATION; CATIONS; METAL;

D O I：

10.1002/cber.19911240712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Elemental gold reacts with UF6 in the presence of CO in anhydrous HF to form quantitatively a complex compound, whose IR spectra and analysis are consistent with the formula [Au(CO)2][UF6].

引用

页码：1559 / 1561

页数：3

共 13 条

[1]

ADELHELM M, 1980, 7TH EUR S FLUOR CHEM

[2]

ADELHELM M, 1980, J FLUORINE CHEM, V19, P586

[3]

ADELHELM M, 1983, UNPUB

[4]

BACHER W, 1986, HDB PHYSICS CHEM ACT, V4, P1

[5] OXIDATION OF SILVER METAL AND SILVER(I) CATIONS BY MOLYBDENUM, TUNGSTEN, AND URANIUM HEXAFLUORIDES AND BY THE NITROSONIUM CATION IN ACETONITRILE - PREPARATION AND PROPERTIES OF SILVER(III) HEXAFLUOROMETALATES(V) [J].

IQBAL, J ;

SHARP, DWA ;

WINFIELD, JM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (03) :461-464

[6] CHEMISTRY OF URANIUM FLUORIDES AND OXIDE FLUORIDES .2. PREPARATION VIBRATIONAL-SPECTRA OF ALPHA AND BETA-URANIUM PENTAFLUORIDE [J].

JACOB, E .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1973, 400 (01) :45-50

[7] SYNTHESIS AND CHARACTERIZATION OF A NEW URANIUM(V) COMPOUND - H3O+UF6- [J].

MASSON, JP ;

DESMOULIN, JP ;

CHARPIN, P ;

BOUGON, R .

INORGANIC CHEMISTRY, 1976, 15 (10) :2529-2531

[8] SYNTHESIS OF BINARY GOLD CARBONYLS, AU(CO)N (N = 1 OR 2) - SPECTROSCOPIC EVIDENCE FOR ISOCARBONYL(CARBONYL)GOLD, A LINKAGE ISOMER OF BIS(CARBONYL)GOLD [J].

MCINTOSH, D ;

OZIN, GA .

INORGANIC CHEMISTRY, 1977, 16 (01) :51-59

[9] LASER RAMAN-SPECTRA OF SOME GROUP-IB METAL-CARBONYL CATIONS [J].

NEPPEL, A ;

HICKEY, JP ;

BUTLER, IS .

JOURNAL OF RAMAN SPECTROSCOPY, 1979, 8 (01) :57-59

[10]

Tobias R.S., 1979, JCE, V56, pA209, DOI [10.1021/ed056pa209, DOI 10.1021/ED056PA209]

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