QUANTUM CONFINEMENT IN NANOMETER-SIZED SILICON CRYSTALLITES

被引:56
作者
ZHAO, XW [1 ]
SCHOENFELD, O [1 ]
KOMURO, S [1 ]
AOYAGI, Y [1 ]
SUGANO, T [1 ]
机构
[1] TOYO UNIV,FAC ENGN,KAWAGOE,SAITAMA 350,JAPAN
来源
PHYSICAL REVIEW B | 1994年 / 50卷 / 24期
关键词
D O I
10.1103/PhysRevB.50.18654
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Picosecond decay and temperature-dependence measurements of violet and blue-light emissions from nanocrystalline-silicon thin films were carried out. The luminescence band exhibits separated peaks at a wavelength region from 350 to 500 nm and shows no intensity degradation. The emission energies of the peaks shift towards the high-energy side at low temperatures by a temperature coefficient similar to single-crystalline silicon. The photoluminescence decays of these emissions can be completely fitted by a double-exponential equation. The two components of the lifetime 1 and 2 determined from the decay curves are 170 and 600 ps, respectively. All the optical events finish within 5 ns. The short lifetimes are suggested to be caused by an enhancement effect on the oscillator strength of the confined levels in zero-dimensionally confined silicon nanometer-sized crystallites. © 1994 The American Physical Society.
引用
收藏
页码:18654 / 18657
页数:4
相关论文
共 15 条
[1]   CAPPED NANOMETER SILICON ELECTRONIC MATERIALS [J].
BRUS, L .
ADVANCED MATERIALS, 1993, 5 (04) :286-288
[2]   TIME-RESOLVED SPECTROSCOPY OF SPONTANEOUS LUMINESCENCE OF CDSSE1-X QUANTUM DOTS [J].
BUGAYEV, A ;
KALT, H ;
KUHL, J ;
RINKER, M .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1991, 53 (01) :75-80
[3]   SILICON QUANTUM WIRE ARRAY FABRICATION BY ELECTROCHEMICAL AND CHEMICAL DISSOLUTION OF WAFERS [J].
CANHAM, LT .
APPLIED PHYSICS LETTERS, 1990, 57 (10) :1046-1048
[4]   ABSORPTION AND EMISSION OF LIGHT IN NANOSCALE SILICON STRUCTURES [J].
HYBERTSEN, MS .
PHYSICAL REVIEW LETTERS, 1994, 72 (10) :1514-1517
[5]   LUMINESCENCE PROPERTIES OF NANOMETER-SIZED SI CRYSTALLITES - CORE AND SURFACE-STATES [J].
KANEMITSU, Y .
PHYSICAL REVIEW B, 1994, 49 (23) :16845-16848
[6]   STEADY-STATE AND TIME-RESOLVED PHOTOLUMINESCENCE IN MICROCRYSTALLINE SILICON [J].
KOMURO, S ;
AOYAGI, Y ;
SEGAWA, Y ;
NAMBA, S ;
MASUYAMA, A ;
KRUANGAM, D ;
OKAMOTO, H ;
HAMAKAWA, Y .
JOURNAL OF APPLIED PHYSICS, 1985, 58 (02) :943-947
[7]  
MASUMOTO Y, 1993, MAT RES S C, V283, P15
[8]  
MATSUMOTO T, 1992, JPN J APPL PHYS PT 2, V31, pL617
[9]   MAGNETIC-FIELD DEPENDENCE OF OPTICAL-ABSORPTION IN SI NANOCRYSTALLITES - A QUANTUM-SIZE EFFECT [J].
NOMURA, S ;
ZHAO, X ;
SCHOENFELD, O ;
MISAWA, K ;
KOBAYASHI, T ;
AOYAGI, Y ;
SUGANO, T .
SOLID STATE COMMUNICATIONS, 1994, 92 (08) :665-668
[10]   ELECTRONIC-STRUCTURE AND OPTICAL-PROPERTIES OF SILICON CRYSTALLITES - APPLICATION TO POROUS SILICON [J].
PROOT, JP ;
DELERUE, C ;
ALLAN, G .
APPLIED PHYSICS LETTERS, 1992, 61 (16) :1948-1950