SYNTHESIS AND CRYSTAL-STRUCTURE OF COBALT(II)-HEXAOXODIPHOSPHATE(P-P)(4-)-DODECAHYDRATE, CO2P2O6-CENTER-DOT-12H2O

被引：14

作者：

HAGEN, S ^{[1
]}

JANSEN, M ^{[1
]}

机构：

[1] UNIV BONN,INST ANORGAN CHEM,D-53121 BONN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 01期

关键词：

HEXAOXODIPHOSPHATE(IV) HYDRATE OF COBALT; SYNTHESIS; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19956210127

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Co2P2O6.12H(2)O was obtained by cleavage and simultaneous oxidation of cyclo-hexaphosphate(III) in a solution of ethanol and aqueous ammonia. The crystal structure has been determined (1898 independent diffractometer data): space group Pbam (No. 55), a = 6.710(2), b = 12.196(2), c = 10.073(3) Angstrom, V = 825.3(1) Angstrom(3), Z = 2, R = 0.060. The P2O64- anions show site symmetry C-2h and are connected to form chains via cobalt. Two cobalt ions together with two sets of four water molecules and two oxygen atoms of P2O64- form pairs of edge connected octahedra. The common edges are formed by the oxygen atoms of the P2O6 groups.

引用

页码：149 / 152

页数：4

共 50 条

[41] New hexachalcogeno-hypodiphosphates of the alkali metals:: Synthesis, crystal structure and vibrational spectra of the hexathiodiphosphate(IV) hydrates K4[P2S6] • 4 H2O, Rb4[P2S6] • 6 H2O, and Cs4[P2S6] • 6 H2O
Gjikaj, Mimoza
Ehrhardt, Claus
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (07): : 1048 - 1054
[42] Synthesis, crystal structure, and proton conductivity of KFe(H2P2O7)2
N. N. Chudinova
E. V. Murashova
A. B. Ilyukhin
V. A. Tarnopol’skii
A. B. Yaroslavtsev
Inorganic Materials, 2005, 41 (1) : 69 - 72
[43] Synthesis and crystal structure of [3,5-(CH3O)2C6H3NH3]4P4O12•4H2O
Aloui, Z
Abid, S
Rzaigui, M
MATERIALS RESEARCH BULLETIN, 2002, 37 (04) : 697 - 703
[44] Crystal structures of Ca(ClO4)(2)center dot 4H(2)O and Ca(ClO4)(2)center dot 6H(2)O
Hennings, Erik
Schmidt, Horst
Voigt, Wolfgang
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 489 - +
[45] Synthesis and Crystal Structure of GaPO4-C4: Ga3P3O12 H2O H2NCH2CH2NH2
Feng Shouhua and Xu Ruren(Department of Chemistry
ChemicalJournalofChineseUniversities, 1988, (02) : 1 - 7
[46] THE FIRST HYDROGENCARBONATES WITH A TRIMERIC [H-2(CO3)(3)](4-) GROUP - PREPARATION AND CRYSTAL-STRUCTURE OF RB4H2(CO3)(3)-CENTER-DOT-H2O AND K4H2(CO3)(3)-CENTER-DOT-1.5H(2)O
CIRPUS, V
ADAM, A
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (07): : 1197 - 1204
[47] Synthesis and Crystal Structure of Complex [La(p-OHC6H4CH2COO)3(phen)]2•2H2O
Xian Chun-Ying
Lin Miao
Pan Wen-Li
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (07) : 1308 - 1311
[48] Synthesis and Crystal Structure of Co（C6NO2H4）3. H2O
ZI Feng-Lan
ZHOU Yin-Zhuang
TU Shu-Jie
LIU Shun-Cheng(Department of Chemistry
结构化学, 1997, (05) : 376 - 379
[49] Crystal structures of trans-[Ta6Cl12(OH)(4)(H2O)(2)]center dot 10H(2)O and (NMe(4))(2)[Ta6Cl12(OH)(6)]center dot 21H(2)O
Beck, U
Simon, A
Sirac, S
Brnicevic, N
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (01): : 59 - 64
[50] THE CRYSTAL-STRUCTURE OF VLODAVETSITE, ALCA2(SO4)(2)F2CL-CENTER-DOT-4H(2)O
STAROVA, GL
FILATOV, SK
MATUSEVICH, GL
FUNDAMENSKY, VS
MINERALOGICAL MAGAZINE, 1995, 59 (394) : 159 - 162

← 1 2 3 4 5 →