INTERCALATION OF N-ALKYLAMINES INTO PEROVSKITE-RELATED LAYERED NIOBIC ACID HBINB2O7-CENTER-DOT-NH(2)O

被引：0

作者：

NAKATO, T ^{[1
]}

NAKADE, M ^{[1
]}

KURODA, K ^{[1
]}

KATO, C ^{[1
]}

机构：

[1] WASEDA UNIV,DEPT APPL CHEM,SHINJUKU KU,TOKYO 169,JAPAN

来源：

ACID-BASE CATALYSIS II | 1994年 / 90卷

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

n-ALkylammonium-HxBiNb2O7 intercalation compounds were synthesized by the reaction of perovskite-related layered oxide HBiNb2O7 . nH(2)O with n-alkylamines. HBiNb2O7 . nH(2)O was not completely converted to the intercalation compounds except for the methylammonium-intercalate. The intercalating capability of HBiNb2O7 . nH(2)O was much lower than those of other previously reported perovskite-related layered niobates such as HCa2O7Nb3O10. The poor reactivity was assumed to be related to unusual irreversible dehydrating behavior of HBiNb2O7 . nH(2)O. On the other hand, the interlayer structure was similar to that of the n-alkylammonium-HxCa2Nb3O10 intercalates in contrast to the difference in the reactivity.

引用

页码：285 / 290

页数：6

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