INTERCALATION OF N-ALKYLAMINES INTO PEROVSKITE-RELATED LAYERED NIOBIC ACID HBINB2O7-CENTER-DOT-NH(2)O

被引：0
|
作者：
NAKATO, T [1 ]
NAKADE, M [1 ]
KURODA, K [1 ]
KATO, C [1 ]
机构：
[1] WASEDA UNIV,DEPT APPL CHEM,SHINJUKU KU,TOKYO 169,JAPAN
来源：
ACID-BASE CATALYSIS II | 1994年 / 90卷
关键词：
D O I：
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
n-ALkylammonium-HxBiNb2O7 intercalation compounds were synthesized by the reaction of perovskite-related layered oxide HBiNb2O7 . nH(2)O with n-alkylamines. HBiNb2O7 . nH(2)O was not completely converted to the intercalation compounds except for the methylammonium-intercalate. The intercalating capability of HBiNb2O7 . nH(2)O was much lower than those of other previously reported perovskite-related layered niobates such as HCa2O7Nb3O10. The poor reactivity was assumed to be related to unusual irreversible dehydrating behavior of HBiNb2O7 . nH(2)O. On the other hand, the interlayer structure was similar to that of the n-alkylammonium-HxCa2Nb3O10 intercalates in contrast to the difference in the reactivity.
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页码：285 / 290
页数：6
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