SYNTHESIS AND CHARACTERIZATION OF TRIAZENIDO AND AMIDINO COMPLEXES OF NICKEL AND PALLADIUM

被引：13

作者：

GOMEZ, M ^{[1
]}

MULLER, G ^{[1
]}

SALES, J ^{[1
]}

机构：

[1] UNIV BARCELONA,DEPT QUIM INORGAN,DIAGONAL 647,E-08028 BARCELONA,SPAIN

来源：

POLYHEDRON | 1993年 / 12卷 / 10期

关键词：

D O I：

10.1016/S0277-5387(00)88208-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of LiPhN(Y)NPh [Y = N or C(Ph)] with [MX2L2] (M = Ni, Pd; X = Cl, Br, mesityl; L = PEt3, a; PMe2Ph, b; PPh3, c; PBz3, d) has been studied. With Y = N complexes containing the triazenido ligand as monodentate [MX(NNN)L2] (Ni: 1; Pd: 2), bidentate [MX(NNN)L] (Ni: 3; Pd: 4) and bridging two metal atoms [M(mu-NNN)L2]2(ClO4)2 (Ni: 5; Pd: 6) have been prepared. However, when Y = C(Ph) only palladium derivatives having the bridging amidino group [Pd(mu-NCN)XL]2 (7) can be obtained. These complexes have been characterized by IR, H-1 and P-31 NMR spectroscopy.

引用

页码：1171 / 1177

页数：7

共 35 条

[1] ALEYA EC, 1969, J AM CHEM SOC, V91, P5761
[2] SYNTHESIS AND STUDY OF MONOMERIC AND DIMERIC AMIDINE COMPLEXES OF NICKEL(II) AND PLATINUM(II) - CRYSTAL-STRUCTURE OF BIS(N,N'-DIPHENYL-BENZAMIDINO)PLATINUM(II), [PT(PHNC(PH)NPH)2]
BARKER, J
KILNER, M
GOULD, RO
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (11): : 2687 - 2694
[3] THE SYNTHESIS, PROPERTIES, AND STRUCTURE OF BIS(AMIDINO)-COMPLEXES OF PALLADIUM - THE CRYSTAL-STRUCTURE OF BIS(N,N'-DI-P-TOLYLACETAMIDINO)PALLADIUM(II)
BARKER, J
CAMERON, N
KILNER, M
MAHOUD, MM
WALLWORK, SC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (07): : 1359 - 1365
[4] BOMBIERI G, 1976, TRANSIT METAL CHEM, V1, P130
[5] CRYSTAL-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)CHLORO-1,3-DI-P-TOLYLTRIAZENIDOPALLADIUM(II)
BOMBIERI, G
IMMIRZI, A
TONIOLO, L
[J]. INORGANIC CHEMISTRY, 1976, 15 (10) : 2428 - 2432
[6] STRUCTURAL STUDIES OF TRIAZENIDO COMPLEXES .1. CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-BIS(TRIPHENYLPHOSPHINE)CARBONYL(1,3-DI-P-TOLYLTRIAZENIDO)HYDRIDORUTHENIUM(II), TRANS-[RU(H)(CH3C6H4N3C6H4CH3)(CO)(P(C6H5)3)2]
BROWN, LD
IBERS, JA
[J]. INORGANIC CHEMISTRY, 1976, 15 (11) : 2788 - 2793
[7] COMPARISON OF MOLECULAR-STRUCTURES OF TRANS-DI(ISOTHIOCYANATO)BIS-(TRIPHENYLPHOSPHINE)PALLADIUM(II) AND TRANS-DI(THIOCYANATO)BIS(TRIPHENYL PHOSPHITE)PALLADIUM(II)
CARTY, AJ
CHIEH, PC
TAYLOR, NJ
WONG, YS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (07): : 572 - 578
[8] ALKYLS AND ARYLS OF TRANSITION METALS .3. NICKEL(II) DERIVATIVES
CHATT, J
SHAW, BL
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1960, (APR): : 1718 - 1729
[9] LIGAND-DEPENDENCE AND OXIDATION STATE-DEPENDENCE OF STRUCTURE IN TRIAZENIDO-BRIDGED COMPLEXES WITH FACE-TO-FACE AND OPEN-BOOK DIRHODIUM CORES - MO STUDIES AND THE CRYSTAL-STRUCTURE OF [RH2(MU-CO)(BIPY)(DPPM)(MU-RNNNR)2][PF6]2.2CH2CL2 (R = P-TOLYL)
CONNELLY, NG
EINIG, T
HERBOSA, GG
HOPKINS, PM
MEALLI, C
ORPEN, AG
ROSAIR, GM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (02) : 143 - 145
[10] AN OCTAHEDRAL COMPLEX CONTAINING 3 4-MEMBERED CHELATE RINGS
CORBETT, M
HOSKINS, BF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (06) : 1530 - &

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