GLASS-LIKE DIELECTRIC-RELAXATION IN CS(5)H(3)(SO(4))(4)H(2)O CRYSTAL

被引：37
作者：
BARANOV, AI
KABANOV, OA
MERINOV, BV
SHUVALOV, LA
DOLBININA, VV
机构：
[1] Institute of Crystalography Acad. Sci., Moscow, USSR
来源：
FERROELECTRICS | 1992年 / 127卷 / 1-4期
关键词：
D O I：
10.1080/00150199208223381
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Results of the single crystal x-ray, dielectric and conductivity studies of Cs5H3(SO4)4H2O are reported. It was shown that a dynamically disordered acid hydrogen bond network is responsible for high protonic conductivity in this crystal. The glass like dielectric dispersion has been detected below 260 K which is probably releated to the freezing of the acid hydrogen bond and water molecules.
引用
收藏
页码：257 / 262
页数：6
相关论文
共 9 条
  • [1] [Anonymous], 1988, FERROELECTRICS
  • [2] Baranov A. I., 1988, FERROELECTRICS, V81, P183, DOI [10.1080/00150198808008840, DOI 10.1080/00150198808008840]
  • [3] BARANOV AI, 1987, IZV AN SSSR FIZ+, V51, P2146
  • [4] BARANOV AI, 1982, PISMA ZH EKSP TEOR F, V36
  • [5] SPIN-LATTICE RELAXATION AND SELF-DIFFUSION STUDY OF THE PROTONIC SUPERIONIC CONDUCTORS CSHSEO4 AND CSHSO4
    BLINC, R
    DOLINSEK, J
    LAHAJNAR, G
    ZUPANCIC, I
    SHUVALOV, LA
    BARANOV, AI
    [J]. PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 1984, 123 (01): : K83 - K87
  • [6] DIELECTRIC-RELAXATION OF MIXED-CRYSTALS OF RB1-X(NH4)XH2PO4 AT MICROWAVE-FREQUENCIES
    BRUCKNER, HJ
    COURTENS, E
    UNRUH, HG
    [J]. ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1988, 73 (03): : 337 - 342
  • [7] SCALING DIELECTRIC DATA ON RB1-X(NH4)XH2PO4 STRUCTURAL GLASSES AND THEIR DEUTERATED ISOMORPHS
    COURTENS, E
    [J]. PHYSICAL REVIEW B, 1986, 33 (04): : 2975 - 2978
  • [8] SCHER H, 1973, PHYS REV B, V7
  • [9] THI MP, 1985, SOLID STATE COMMUN, P55
1