PALLADIUM-CATALYZED ARYLATION OF FERROCENE DERIVATIVES - A CONVENIENT HIGH-YIELD ROUTE TO 1,1'-BIS(HALOPHENYL)FERROCENES

被引：64

作者：

KNAPP, R ^{[1
]}

REHAHN, M ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST POLYMER,KAISERSTR 12,W-7500 KARLSRUHE,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 452卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83196-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Pd-catalyzed cross-coupling reaction between halobenzenes and ferrocene-1,1'-diboronic acid is reported. Condensation proceeds smoothly to give 1,1'-diphenyl- and 1,1'-bis(halophenyl)-substituted ferrocenes bearing fluoro, chloro and bromo substituents in good yields. An effective synthesis of the intermediate ferrocene-1,1'-diboronic acid is described.

引用

页码：235 / 240

页数：6

共 38 条

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