A NEW CATALYTIC-SYSTEM FOR THE DIRECT OXIDATION OF OLEFINS TO 1,2-DIOLS BY DIOXYGEN IN AQUEOUS-MEDIUM

被引：9

作者：

BENVENUTO, MA ^{[1
]}

SEN, A ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT CHEM,UNIV PK,PA 16802

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期

关键词：

D O I：

10.1039/c39930000970

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In aqueous medium, in the presence of dioxygen, metallic platinum is found to catalyse the oxidation of ethylene and propene to a mixture of ethane-1,2-diol and acetic acid, and propane-1,2-diol and acetone, respectively; only the 1,2-diol was formed, however, when carbon monoxide was added to the reaction mixture.

引用

页码：970 / 972

页数：3

共 13 条

[1]

AUSTIN RG, 1985, CHEM IND, V22, P269

[2] KINETICS OF CO OXIDATION ON SINGLE-CRYSTAL PD, PT, AND IR [J].