HOMOGENEOUS RHODIUM COMPLEX-CATALYZED HYDROFORMYLATION AND RELATED REACTIONS OF FUNCTIONALLY SUBSTITUTED OLEFINS

被引：28

作者：

TRZECIAK, AM ^{[1
]}

ZIOLKOWSKI, JJ ^{[1
]}

机构：

[1] WROCLAW B BEIRUT UNIV,INST CHEM,PL-50383 WROCLAW,POLAND

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1987年 / 43卷 / 01期

关键词：

ALCOHOLS - Hydrogenation - CATALYSIS - CHEMICAL REACTIONS - Isomerization - OLEFINS - Processing;

D O I：

10.1016/0304-5102(87)87015-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The following rhodium (I) complexes were applied as catalysts for homogeneous hydroformylation, isomerisation and hydrogenation of allyl alcohol, methyl acrylate and vinyl acetate: Rh(acac)P//2, Rh(acac)(CO)//2, HRhP//4 and RhP//3P prime (P equals P(OPh)//3; P prime equals P(OPh)//2(OC//6H//4)). All reactions occur at relatively mild conditions: 1 atm H//2 or (CO plus H//2) pressure and 20-40 degree C, and demonstrate high catalytic activity of catalysts used.

引用

页码：15 / 20

页数：6

共 16 条

[11] LOW-PRESSURE, HIGHLY-ACTIVE RHODIUM CATALYST FOR THE HOMOGENEOUS HYDROFORMYLATION OF OLEFINS [J].

TRZECIAK, AM ;

ZIOLKOWSKI, JJ .

JOURNAL OF MOLECULAR CATALYSIS, 1986, 34 (02) :213-219

[12] REACTIONS OF THE ORTHO-METALATED RHODIUM(I) COMPLEX OF THE FORMULA RH[P(OC6H4)(OPH)2][P(OPH)3]3 WITH HX MOLECULES [J].

TRZECIAK, AM ;

ZIOLKOWSKI, JJ .

TRANSITION METAL CHEMISTRY, 1985, 10 (10) :385-386

[13]

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[14] SYNTHESIS OF RHODIUM(I) ACETYLACETONATO-BIS-TRIPHENYLPHOSPHITE COMPLEX AND ITS REACTIVITY TOWARDS CARBON-MONOXIDE [J].

TRZECIAK, AM ;

ZIOLKOWSKI, JJ .

INORGANICA CHIMICA ACTA-LETTERS, 1982, 64 (06) :L267-L268

[15] KINETIC AND SPECTROSCOPIC STUDIES OF THE SUBSTITUTION-REACTIONS OF [RH(ACAC)(CO)2] WITH TRIPHENYLPHOSPHITE [J].

VANELDIK, R ;

AYGEN, S ;

KELM, H ;

TRZECIAK, AM ;

ZIOLKOWSKI, JJ .

TRANSITION METAL CHEMISTRY, 1985, 10 (05) :167-171

[16]

VARSHAVSKII YS, 1967, ZH NEORG KHIM, V12, P1703

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