THE COPPER(II) COMPLEX WITH THE IMIDAZOLE-BOUND HISTAMINE DERIVATIVE OF BETA-CYCLODEXTRIN AS A POWERFUL CHIRAL DISCRIMINATING AGENT

被引：53

作者：

CUCINOTTA, V ^{[1
]}

DALESSANDRO, F ^{[1
]}

IMPELLIZZERI, G ^{[1
]}

VECCHIO, G ^{[1
]}

机构：

[1] CNR,IST STUDIO SOSTANZE NAT INTERESSE ALIMENTARE & CHIM FARMACEUT,I-95125 CATANIA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 23期

关键词：

D O I：

10.1039/c39920001743

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The newly synthesized 6-derivative of beta-cyclodextrin with histamine, bound through the N-1 of imidazole was used as a ligand for copper(II) ion, the ligand being characterized by NMR spectroscopy and the copper(II) complex by EPR spectroscopy; the complex was used in chiral ligand exchange chromatography and was able to separate L- and D-tryptophan.

引用

页码：1743 / 1745

页数：3

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