ROTATIONAL SPECTRUM OF THE PH3 MOLECULE IN THE NU-2 = 1 VIBRATIONAL-STATE

被引：10

作者：

BURENIN, AV ^{[1
]}

FUSINA, L ^{[1
]}

CARLOTTI, M ^{[1
]}

机构：

[1] DIPARTIMENTO CHIM FIS & INORGAN,I-40136 BOLOGNA,ITALY

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1993年 / 160卷 / 01期

关键词：

D O I：

10.1006/jmsp.1993.1160

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A representation of the effective rotational Hamiltonian in the form of optimum versions of a rational series of the perturbation theory is suggested for nonisolated molecular states. This representation is used to analyse the most complete set of precise transition frequencies in the rotational spectrum of the PH3 molecule in thc v2 = 1 state. Most of the experimental data were obtained for the first time using a Michelson interferometer in the wave number range 40-130 cm-1. © 1993 Academic Press, Inc.

引用

页码：97 / 104

页数：8

共 16 条

[1] CALCULATED SEXTIC CENTRIFUGAL-DISTORTION CONSTANTS OF POLYATOMIC-MOLECULES [J].

ALIEV, MR ;

WATSON, JKG .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1976, 61 (01) :29-52

[2]

[Anonymous], 1982, MOL VIBRATIONAL ROTA

[3] A NEW APPROACH TO THE TREATMENT OF ROTATIONAL SPECTRA OF MOLECULES WITH SMALL MOMENTS OF INERTIA APPLIED TO THE PH3 MOLECULE IN THE GROUND-STATE [J].

BELOV, SP ;

BURENIN, AV ;

POLYANSKY, OL ;

SHAPIN, SM .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1981, 90 (02) :579-589

[4] A NEW SCHEME FOR THE REDUCTION OF THE EFFECTIVE ROTATIONAL HAMILTONIAN OF A SYMMETRIC TOP-TYPE MOLECULE IN A NONDEGENERATE VIBRATIONAL-STATE [J].

BURENIN, AV .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1990, 142 (01) :117-121

[5] OPTIMUM RATIONAL PERTURBATION-THEORY SERIES WHEN TREATING ROTATIONAL SPECTRA OF NONLINEAR MOLECULES [J].

BURENIN, AV .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1990, 140 (01) :54-61

[6]

BURENIN AV, 1989, OPT SPEKTROSK+, V66, P52

[7]

BURENIN AV, 1983, OPT SPEKTROSK+, V54, P436

[8]

BURENIN AV, 1991, OPT SPEKTROSK+, V71, P266

[9] OPTIMUM RATIONAL VERSIONS OF EFFECTIVE ROTATIONAL HAMILTONIAN OPERATOR OF THE SYMMETRICAL TOP-TYPE MOLECULE - APPLICATION TO THE PH3 MOLECULE IN THE GROUND-STATE [J].

BURENIN, AV .

MOLECULAR PHYSICS, 1992, 75 (02) :305-309

[10] ON THE CONVERGENCE OF RATIONAL SERIES WHEN TREATING SPECTRA OF QUANTUM-SYSTEMS [J].

BURENIN, AV .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1989, 136 (01) :169-172

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