REACTION OF DIAZOALKANES WITH UNSATURATED-COMPOUNDS .11. RELATIVE REACTIVITY OF OLEFINS ON CATALYTIC CYCLOPROPANATION WITH DIAZOMETHANE AND PALLADIUM CATALYSTS

被引：6

作者：

DZHEMILEV, UM ^{[1
]}

DOKICHEV, VA ^{[1
]}

SULTANOV, SZ ^{[1
]}

KHURSAN, SL ^{[1
]}

NEFEDOV, OM ^{[1
]}

TOMILOV, YV ^{[1
]}

KOSTITSYN, AB ^{[1
]}

机构：

[1] ND ZELINSKII INST ORGAN CHEM,MOSCOW 117913,RUSSIA

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 10期

基金：

新加坡国家研究基金会;

关键词：

UNSATURATED COMPOUNDS; CYCLOPROPANES; METAL-COMPLEX CATALYSIS; DIAZOMETHANE; RELATIVE REACTIVITY;

D O I：

10.1007/BF00863821

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The relative reactivity of unsaturated compounds on catalytic cyclopropanation with diazomethane in the presence of catalysts based on Pd2+ [Pd(OAC)2, Pd(acac)2, (PPh3)2.PdCl2] has been studied using competing reactions. An interconnection was shown between the relative reactivity of the olefins and the coordinating activity of the C=C bond depending on its strain and spatial environment.

引用

页码：1846 / 1852

页数：7

共 20 条

[1] Benson S.W., 1976, THERMOCHEMICAL KINET
[2] PHOTOELECTRON SPECTROSCOPY OF INTERACTION BETWEEN NON-CONJUGATED DOUBLE BONDS
BISCHOF, P
HASHMALL, JA
HEILBRON.E
HORNUNG, V
[J]. HELVETICA CHIMICA ACTA, 1969, 52 (06) : 1745 - &
[3] GROUND-STATES OF MOLECULES .39. MNDO RESULTS FOR MOLECULES CONTAINING HYDROGEN, CARBON, NITROGEN, AND OXYGEN
DEWAR, MJS
THIEL, W
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) : 4907 - 4917
[4] GROUND-STATES OF MOLECULES .38. MNDO METHOD - APPROXIMATIONS AND PARAMETERS
DEWAR, MJS
THIEL, W
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (15) : 4899 - 4907
[5] DOLGY IE, 1989, CHEM CARBENS SMALL S, P101
[6] Dzhemilev U. M., 1989, IAN SSSR KH, P1861
[7] GLEITER R, 1979, TOP CURR CHEM, V86, P197
[8] EXCEPTIONAL REACTIVITY OF THE BICYCLO[2.2.1]HEPTENE DOUBLE-BOND
HUISGEN, R
OOMS, PHJ
MINGIN, M
ALLINGER, NL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (11) : 3951 - 3953
[9] A UV PHOTOELECTRON SPECTROSCOPIC AND HARTREE-FOCK-SLATER MO-LCAO STUDY OF TETRACYCLO[3.3.0.02,4.03,6]OCT-7-ENE AND RELATED STRAINED COMPOUNDS
JONKERS, G
VANDERMEER, WJ
DELANGE, CA
BAERENDS, EJ
STAPERSMA, J
KLUMPP, GW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) : 587 - 590
[10] KAZIMIRCHUK IV, 1984, ZH ORG KHIM+, V20, P1221

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