REACTIONS OF COBALT CARBONYL CATALYSTS IN METHANOL UNDER SYNGAS PRESSURE

被引：11

作者：

MIRBACH, MF ^{[1
]}

MIRBACH, MJ ^{[1
]}

机构：

[1] UNIV PETR & MINERALS,DEPT CHEM,DHAHRAN,SAUDI ARABIA

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1985年 / 33卷 / 01期

关键词：

METHANOL;

D O I：

10.1016/0304-5102(85)85014-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The authors have studied the influence of methanol on cobalt carbonyls under the conditions of the catalytic reactions, e. g. elevated temperatures and pressures, using on-line IR and UV spectroscopy. A description is given of results obtained for the system cobalt carbonyl/methanol/CO/H//2 and the influence of olefins and KI. The consequences of findings on the mechanisms of the homologation of methanol and the hydroformylation are also discussed.

引用

页码：23 / 35

页数：13

共 43 条

[1] STUDY OF MECHANISM OF HYDROFORMYLATION AT INDUSTRIAL REACTION CONDITIONS .3. MECHANISM OF HYDROFORMYLATION [J].