EXPLORATORY RING-OPENING POLYMERIZATION - RING-OPENING POLYMERIZATION OF VINYLKETENE CYCLIC ACETAL

被引：11
作者：
CHO, I
KIM, SK
机构：
[1] Korea Advanced Inst of Science and, Technology, Seoul
来源：
JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS | 1990年 / 28卷 / 13期
关键词：
D O I：
10.1002/pol.1990.140281304
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The authors have previously reported that a certain ketene cyclic acetal such as 2-methylene-4-phenyl-1,3-dioxolane undergoes radical ring-opening polymerization to afford the corresponding polyester. To explore furhter the possibility of ring-opening polymerization of other types of ketene cyclic acetals, the authors were interested in vinylketene cyclic acetal with phenyl substituent as in the case of highly reactive 2-methylene-4-phenyl-1,3-dioxolane. In this article, the synthesis and polymerization of 4-phenyl-2-propenylene-1,3-dioxolane (I) are described.
引用
收藏
页码：417 / 421
页数：5
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