(Z)-2-(2-Oxoindolin-3-ylidene)-N-phenylhydrazinecarbothioamide

被引:9
作者
Ali, Amna Qasem [1 ,2 ]
Eltayeb, Naser Eltaher [3 ]
Teoh, Siang Guan [1 ]
Salhin, Abdussalam [1 ]
Fun, Hoong-Kun [4 ]
机构
[1] Univ Sains Malaysia, Sch Chem Sci, Minden, Penang, Malaysia
[2] Sabha Univ, Fac Sci, Sabha, Libya
[3] Int Univ Africa, Dept Chem, Khartoum, Sudan
[4] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, Usm 11800, Penang, Malaysia
关键词
D O I
10.1107/S160053681200400X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C15H12N4OS, the dihedral angle between the nine-membered indolin-2-one ring system and the phenyl ring is 2.72 (7)degrees. Intramolecular cyclic N-H center dot center dot center dot O and C-H center dot center dot center dot S hydrogen-bonding interactions [graph set S(6)] are present, as are weak N-H center dot center dot center dot N interactions [graph set S(5)]. In the crystal, molecules form centrosymmetric cyclic dimers through pairs of N-H center dot center dot center dot O hydrogen bonds [graph set R-2(2)(8)] and these are extended by C-H center dot center dot center dot S interactions. The crystal structure also features weak C-H center dot center dot center dot pi interactions.
引用
收藏
页码:O962 / +
页数:8
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