X-RAY-DIFFRACTION STUDY OF POLY(3-N.DECYLPYRROLE), POLYPYRROLE, AND THEIR MONOMERS

被引：11
作者：
PETRILLO, C
BORRA, S
CAGNOLATI, R
RUGGERI, G
机构：
[1] SCUOLA NORMALE SUPER PISA,I-56100 PISA,ITALY
[2] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,I-56124 PISA,ITALY
来源：
JOURNAL OF CHEMICAL PHYSICS | 1994年 / 101卷 / 12期
关键词：
D O I：
10.1063/1.467851
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The structure of the organic intrinsically conducting polymers polypyrrole and poly(3-n.decylpyrrole) was investigated by x-ray diffraction. The liquid monomers pyrrole and 3-n.decylpyrrole were also measured. From the analysis of all the data, information on the molecular and intermolecular correlations in the polymers was obtained. Both the polymeric systems are found to maintain a substantial planarity of the aromatic rings, i.e., the alkylic substituent in poly(3-n.decylpyrrole) does not affect the planarity of the compound. Possible effects related to the size of the counterion are also discussed. © 1994 American Institute of Physics.
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页码：11004 / 11011
页数：8
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