REACTIONS OF NINHYDRIN WITH ACTIVATED ANILINES - FORMATION OF INDOLE-DERIVATIVES

被引：43

作者：

BLACK, DS

BOWYER, MC

CONDIE, GC

CRAIG, DC

KUMAR, N

机构：

[1] School of Chemistry, University of New South Wales, Sydney

来源：

TETRAHEDRON | 1994年 / 50卷 / 37期

关键词：

D O I：

10.1016/S0040-4020(01)85709-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In benzene, ninhydrin undergoes electrophilic substitution at C2 of 3,5-dimethoxyaniline, leading to the indeno[1,2b]indole (7), which can in turn be transformed into the fused indole derivatives (9), (17) and (19), the indolenines (15) and (16), the indolone (18), and the dihydroindole(8). The corresponding reaction in water undergoes electrophilic substitution at C4 to give compound (11)

引用

页码：10983 / 10994

页数：12

共 14 条

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