CONTROL OF STEREOCHEMISTRY IN POTASSIUM ALKOXIDE ACCELERATED [1,3] SIGMATROPIC REARRANGEMENTS BY THE USE OF A CROWN ETHER FOR THE APPARENT DESTRUCTION OF ION-PAIRS - EVIDENCE FOR A FRAGMENTATION MECHANISM IN A VINYLCYCLOBUTANE REARRANGEMENT

被引：29

作者：

BHUPATHY, M ^{[1
]}

COHEN, T ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1983年 / 105卷 / 23期

关键词：

D O I：

10.1021/ja00361a048

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：6978 / 6979

页数：2

共 7 条

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[5] 2-ALKENYL ANIONS AND THEIR SURPRISING ENDO PREFERENCE - FACILE AND EXTREME STEREOCONTROL OVER CARBON-CARBON LINKING REACTIONS WITH ORGANOMETALLICS OF ALLYL TYPE [J].

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[6] FRAGMENTATION OF HOMOALLYLIC ALKOXIDES - SYNTHESIS OF PROPENYL AND 2-METHYLPROPENYL KETONES FROM CARBOXYLIC ESTERS [J].

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[7] [1,3] SHIFTS OF POTASSIUM ALKOXIDES - BICYCLO[3.2.0]HEPTENE-NORBORNENE TRANSFORMATION [J].

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