MECHANISTIC STUDIES OF ATOM TRANSFER ADDITION-REACTIONS OF IODOMALONONITRILES TO ALKENES - 1,2-ASYMMETRIC INDUCTION IN AN IODINE ATOM TRANSFER-REACTION

被引：30

作者：

CURRAN, DP

THOMA, G

机构：

[1] Department of Chemistry, University of Pittsburgh, Pittsburgh

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 44期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/0040-4039(91)80154-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unusual stereoselective iodine transfer to a benzylic radical helps to show that atom transfer additions of iodomalononitriles to alkenes occur by a radical mechanism.

引用

页码：6307 / 6310

页数：4

共 13 条

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[5] ATOM TRANSFER CYCLIZATION REACTIONS OF ALPHA-IODO ESTERS, KETONES, AND MALONATES - EXAMPLES OF SELECTIVE 5-EXO, 6-ENDO, 6-EXO, AND 7-ENDO RING CLOSURES [J].

CURRAN, DP ;

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[6]

CURRAN DP, UNPUB TETRAHEDRON

[7]

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[8] FREE-RADICAL CYCLIZATIONS - APPLICATION TO THE TOTAL SYNTHESIS OF DL-PLEUROTIN AND DL-DIHYDROPLEUROTIN ACID [J].

HART, DJ ;

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KRISHNAMURTHY, R ;

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) :7507-7519

[9]

HART DJ, 1991, SYBNLETT, P425

[10]

NEWCOMB M, 1988, ACCOUNTS CHEM RES, V21, P201

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