1-AZA-1,3-BIS(TRIPHENYLPHOSPHORANYLIDENE)PROPANE - A NOVEL =CHCH2N= SYNTHON

被引：125

作者：

KATRITZKY, AR ^{[1
]}

JIANG, JL ^{[1
]}

STEEL, PJ ^{[1
]}

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 16期

关键词：

D O I：

10.1021/jo00095a034

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1-Aza-1,3-bis(triphenylphosphoranylidene)propane (3), prepared in situ by the reaction of 1-[[(triphenylphosphoranylidene)amino]methyl]benzotriazole (betmip, 4) with methylidenetriphenylphosphorane followed by treatment with butyllithium, enables convenient preparations of 3H-2-benzazepine (7), 2,3-diarylpyrroles 8, and primary allylamines 12 and 13.

引用

页码：4551 / 4555

页数：5

共 24 条

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