SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF THE NEUTRAL METAL FORMYL (ETA-5-C5ME5)(CO)2(PPH3)MOCHO - A NEW ROUTE TO MONOCATIONIC SECONDARY ALKOXYCARBENE COMPLEXES [(ETA-5-C5ME5)(CO)2(PPH3)MO(CHOH)]+X-, [(ETA-5-C5ME5)(CO)2(PPH3)MO(CHOME)]+X-

被引：22

作者：

ASDAR, A ^{[1
]}

LAPINTE, C ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM ORGANOMET LAB,CNRS,UNITE 415,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1987年 / 327卷 / 02期

关键词：

D O I：

10.1016/0022-328X(87)80214-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：C33 / C36

页数：4

共 16 条

[1]

ASDAR A, UNPUB

[2] UPON THE MECHANISM OF THE HOMOGENEOUS HYDROGENATION OF CARBON-MONOXIDE [J].

BARRATT, DS ;

COLEHAMILTON, DJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 306 (02) :C41-C44

[3] STEPWISE REDUCTION OF THIOCARBONYL LIGAND-HYDRIDE TRANSFER TO CS-THIOFORMYL, THIOFORMALDEHYDE, METHYLTHIOLATO, SECONDARY CARBENE, FORMYL AND IMINOFORMYL COMPLEXES OF OSMIUM [J].

COLLINS, TJ ;

ROPER, WR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 159 (01) :73-89

[4] ORGANOMETALLIC CONFORMATIONAL EQUILIBRIA .11. CIS-TRANS ISOMERISM AND STEREOCHEMICAL NONRIGIDITY IN CYCLOPENTADIENYLMOLYBDENUM COMPLEXES [J].

FALLER, JW ;

ANDERSON, AS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (20) :5852-&

[5] NUCLEOPHILIC ADDITIONS TO A METAL-CARBONYL CATION - SYNTHESIS OF METALLOCARBOXYLATE AND FORMYL COMPLEXES OF MOLYBDENUM [J].

GIBSON, DH ;

OWENS, K ;

ONG, TS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (04) :1125-1127

[6] SPECTROSCOPIC CHARACTERIZATION OF UNSTABILIZED ELECTROPHILIC IRON METHYLENE AND IRON HYDROXYMETHYLENE COMPLEXES [(ETA-5-C5ME5)FE(CO)2CH2]+, [(ETA-5-C5ME5)FE(CO)2CHOH]+ - HYDRIDE ABSTRACTION VS ELECTRON-TRANSFER MECHANISM [J].

GUERCHAIS, V ;

LAPINTE, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) :663-664

[7] SPECTROSCOPIC CHARACTERIZATION OF ELECTROPHILIC D4 METHYLENE AND BENZYLIDENE COMPLEXES OF THE TYPE CP(CO)2(L)M=CHR+ (L = PPH3, PET3 - M = MO, W - R = H, PH) - EXPERIMENTAL-DETERMINATION OF BARRIERS TO ROTATION ABOUT THE TUNGSTEN-METHYLENE MULTIPLE BOND [J].

KEGLEY, SE ;

BROOKHART, M ;

HUSK, GR .

ORGANOMETALLICS, 1982, 1 (05) :760-762

[8]

KING RB, 1976, COORD CHEM REV, V20, P55

[9] THE MOLECULAR-STRUCTURE OF [MO(CO)3H(ETA-C5ME5)] AND ITS CONVERSION TO [MO(CO)3CL(ETA-C5ME5)] AND [LI(ME2NCH2CH2NME2)2][MO(CO)3(ETA-C5ME5)] [J].

LEONI, P ;

GRILLI, E ;

PASQUALI, M ;

TOMASSINI, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (05) :1041-1043

[10] CARBON-MONOXIDE ACTIVATION BY IRIDIUM(III) DICATIONIC CARBONYL-COMPLEXES [J].

LILGA, MA ;

IBERS, JA .

ORGANOMETALLICS, 1985, 4 (03) :590-598

← 1 2 →