PREPARATION AND REGIOSELECTIVE AND DIASTEREOSELECTIVE REACTIONS OF ALLYLIC ZIRCONIUM REAGENTS FROM ALLYLIC ETHER DERIVATIVES

被引：77

作者：

ITO, H ^{[1
]}

TAGUCHI, T ^{[1
]}

HANZAWA, Y ^{[1
]}

机构：

[1] TOKYO COLL PHARM,1432-1 HORINOUCHI,HACHIOJI,TOKYO 19203,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 10期

关键词：

ZIRCONOCENE; ZIRCONACYCLES; ALLYLIC ETHER DERIVATIVES; ALLYLIC ZIRCONIUM REAGENT; HOMOALLYLIC ALCOHOL DERIVATIVES;

D O I：

10.1016/S0040-4039(00)91605-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylic zirconium reagents were generated by treating allylic ether derivatives with zirconocene ''Cp2Zr''. The allylic zirconium reagents reacted with aldehydes in highly regio- and diastereoselective manner to give homoallylic alcohol compounds.

引用

页码：1295 / 1298

页数：4

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