HIGHLY SELECTIVE CROSS-COUPLING REACTIONS OF ORGANOSILICON COMPOUNDS MEDIATED BY FLUORIDE-ION AND A PALLADIUM CATALYST

被引：2

作者：

HATANAKA, Y ^{[1
]}

HIYAMA, T ^{[1
]}

机构：

[1] SAGAMI CHEM RES CTR,4-4-1 NISHIOHNUMA,SAGAMIHARA,KANAGAWA 229,JAPAN

来源：

SYNLETT | 1991年 / 12期

关键词：

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organosilicon compounds couple with organic halides or triflates in the presence of a fluoride ion promoter and a palladium catalyst. This reaction is in general highly chemoselective and stereospecific. In addition to carbon-carbon bond formation, carbon-silicon bond formation is realized. Synthetic examples mainly from our Laboratories are reviewed with the emphasis on the mechanism and stereochemistry of transmetalation from silicon to palladium.

引用

页码：845 / 853

页数：9

共 60 条

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