DETERMINATION OF THE FREE-ION YIELD IN PHOTOINDUCED ELECTRON-TRANSFER PROCESSES USING TRANSIENT THERMAL PHASE GRATING SPECTROSCOPY

被引：23

作者：

HENSELER, A ^{[1
]}

VAUTHEY, E ^{[1
]}

机构：

[1] UNIV FRIBOURG,INST PHYS CHEM,CH-1700 FRIBOURG,SWITZERLAND

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1995年 / 91卷 / 01期

关键词：

PHOTOTHERMAL SPECTROSCOPY; ENERGETICS OF ELECTRON TRANSFER; TRIPLET YIELD; NONRADIATIVE TRANSITIONS;

D O I：

10.1016/1010-6030(95)04111-R

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An application of transient thermal phase grating spectroscopy with near-infrared probing to the determination of free ion yield in photoinduced electron transfer reactions is presented. The model system is 9, 10-dicyanoanthracene with various electron donors in acetonitrile. The measured yields are in good agreement with those obtained from photoconductivity, when the latter are correctly calibrated. The method is explained and its advantages and limitations are discussed.

引用

页码：7 / 12

页数：6

共 48 条

[1] PICOSECOND TRANSIENT THERMAL PHASE GRATING STUDY OF A PHOTOINDUCED ELECTRON-TRANSFER REACTION IN SOLUTION
VAUTHEY, E
HENSELER, A
JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (21): : 8652 - 8660
[2] THE RELIABILITY OF FREE-ION YIELD IN PHOTOINDUCED ELECTRON-TRANSFER REACTIONS - THE MODEL SYSTEM 9,10-DICYANOANTHRACENE BIPHENYL IN ACETONITRILE
VAUTHEY, E
PILLOUD, D
HASELBACH, E
SUPPAN, P
JACQUES, P
CHEMICAL PHYSICS LETTERS, 1993, 215 (1-3) : 264 - 268
[3] FREE-ENERGY DEPENDENCE OF THE ION YIELD OF PHOTOINDUCED ELECTRON-TRANSFER REACTIONS IN SOLUTION
VAUTHEY, E
SUPPAN, P
HASELBACH, E
HELVETICA CHIMICA ACTA, 1988, 71 (01) : 93 - 99
[4] INITIATION OF FREE-RADICAL POLYMERIZATION BY PHOTOINDUCED ELECTRON-TRANSFER PROCESSES
LEDWITH, A
PURBRICK, MD
POLYMER, 1973, 14 (10) : 521 - 522
[5] Thermal diffusivity determination using heterodyne phase insensitive transient grating spectroscopy
Dennett, Cody A.
Short, Michael P.
JOURNAL OF APPLIED PHYSICS, 2018, 123 (21)
[6] Thermal diffusivity determination using heterodyne phase insensitive transient grating spectroscopy
1600, American Institute of Physics Inc. (123):
[7] FREE ENTHALPY DEPENDENCE OF FREE-RADICAL YIELD OF PHOTOINDUCED ELECTRON-TRANSFER IN ACETONITRILE
KIKUCHI, K
TAKAHASHI, Y
HOSHI, M
NIWA, T
KATAGIRI, T
MIYASHI, T
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (06): : 2378 - 2381
[8] Transient absorption spectroscopy for photoinduced electron transfer processes of pyrromethene 546
Brandt, Nathaniel C.
Brom, Joseph M.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 229 - 229
[9] APPLICATION OF TRANSIENT RESONANCE RAMAN-SPECTROSCOPY TO THE STRUCTURE OF A PHOTOINDUCED ELECTRON-TRANSFER INTERMEDIATE
SCHOONOVER, JR
CHEN, PY
BATES, WD
DYER, RB
MEYER, TJ
INORGANIC CHEMISTRY, 1994, 33 (04) : 793 - 797
[10] PHOTOINDUCED ELECTRON-TRANSFER AND BACK TRANSFER IN SYSTEMS OF RANDOMLY DISTRIBUTED DONORS AND ACCEPTORS - PICOSECOND TRANSIENT GRATING EXPERIMENTS
DORFMAN, RC
LIN, Y
ZIMMT, MB
BAUMANN, J
DOMINGUE, RP
FAYER, MD
JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (15): : 4258 - 4260

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