BECKMANN REARRANGEMENT CATALYZED BY THE COMBINED USE OF TETRABUTYLAMMONIUM PERRHENATE(VII) AND TRIFLUOROMETHANESULFONIC ACID

被引：44

作者：

NARASAKA, K ^{[1
]}

KUSAMA, H ^{[1
]}

YAMASHITA, Y ^{[1
]}

SATO, H ^{[1
]}

机构：

[1] SUMITOMO CHEM CO LTD, EHIME RES LAB, NIIHAMA, EHIME 792, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.489

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Beckmann reaffangement of oximes is catalyzed with tetrabutylammonium perrhenate(VII), trifluoromethanesulfonic acid and hydroxylamine hydrochloride in nitromethane under azeotropic conditions, giving amides in high yield.

引用

页码：489 / 492

页数：4

共 7 条

[1]

Gawley R.E, 2004, ORG REACT, DOI 10.1002/0471264180.or035.01

[2]

HARADA T, 1991, SYNTHESIS-STUTTGART, P1216

[3] VAPOR-PHASE BECKMANN REARRANGEMENT OF CYCLOHEXANONE OXIME OVER BORIA-HYDROXYAPATITE CATALYST [J].

IZUMI, Y ;

SATO, S ;

URABE, K .

CHEMISTRY LETTERS, 1983, (10) :1649-1652

[4] CATALYTIC BECKMANN REARRANGEMENT OF OXIMES IN HOMOGENEOUS LIQUID-PHASE [J].

IZUMI, Y .

CHEMISTRY LETTERS, 1990, (12) :2171-2174

[5] THE CATALYTIC BECKMANN REARRANGEMENT OF KETOXIME TRIMETHYLSILYL ETHERS USING AN ANTIMONY(V) SALT [J].

MUKAIYAMA, T ;

HARADA, T .

CHEMISTRY LETTERS, 1991, (09) :1653-1656

[6] REARRANGEMENT OF ALLYLIC AND PROPARGYLIC ALCOHOLS CATALYZED BY THE COMBINED USE OF TETRABUTYLAMMONIUM PERRHENATE(VII) AND PARA-TOLUENESULFONIC ACID [J].

NARASAKA, K ;

KUSAMA, H ;

HAYASHI, Y .

TETRAHEDRON, 1992, 48 (11) :2059-2068

[7] REARRANGEMENT OF ALLYLIC AND PROPARGYLIC ALCOHOLS CATALYZED BY THE COMBINED USE OF TETRABUTYLAMMONIUM PERRHENATE(VII) AND PARA-TOLUENESULFONIC ACID [J].

NARASAKA, K ;

KUSAMA, H ;

HAYASHI, Y .

CHEMISTRY LETTERS, 1991, (08) :1413-1416

← 1 →