NEW SYNTHESIS OF DIARYLALKYNES FROM 1-(ARYLMETHYL)BENZOTRIAZOLES AND ARYLIDENEAMINES

被引：13

作者：

KATRITZKY, AR

GORDEEV, MF

机构：

[1] Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1992年 / 11期

关键词：

D O I：

10.1039/p19920001295

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Michael addition of lithio derivatives 2 of 1-(arylmethyl)benzotriazoles 1 to arylideneamines 3-5 gave the corresponding 1-(benzotriazol-1-yl)-2-anilino (or tosylamino)-1,2-diarylethanes 6-8. The latter were shown to undergo a double elimination reaction under the action of Bu(t)OK in DMF to afford diarylalkynes in high yields.

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页码：1295 / 1298

页数：4

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