NOE CORRELATIONS IN MTPA, MNCB AND MBNC ESTERS

被引：21
作者：
FUKUSHI, Y
YAJIMA, C
MIZUTANI, J
机构：
[1] Department of Applied Bioscience, Faculty of Agriculture, Hokkaido University, Kita-ku, Sapporo
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 50期
关键词：
D O I：
10.1016/S0040-4039(00)78558-3
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
NOEs are observed between the protons of the acid moieties and the protons of the alcohol moieties in some alpha-methoxy-alpha-trifluoromethylphenylacetic acid (MTPA, 1), 2-(2'-methoxy-1'naphthyl)-3-5,dichlorobenzoic acid (MNCB, 2), and 2'-methoxy-1,1'-binaphthyl-2-carboxylic acid (MBNC, 3) esters. This initial observation could be another clue to determine the absolute configurations of chiral alcohols.
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收藏
页码：9417 / 9420
页数：4
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