HYDROGEN-BONDING IN TERNARY POLYMER BLEND SYSTEMS - DETERMINATION OF ASSOCIATION PARAMETERS

被引：22
作者：
LEMENESTREL, C
BHAGWAGAR, DE
PAINTER, PC
COLEMAN, MM
GRAF, JF
机构：
[1] PENN STATE UNIV,DEPT MAT SCI & ENGN,UNIV PK,PA 16802
[2] GEC LTD,PARKERSBURG,WV 26181
来源：
MACROMOLECULES | 1992年 / 25卷 / 26期
关键词：
D O I：
10.1021/ma00052a005
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polymer blend system consisting of poly(4-vinylphenol)(PVPh), poly(vinylacetate)(PVAc), and poly(ethylene oxide) (PEO) represents a rare case of a ternary system in which each binary pair is miscible in the amorphous state at 150-degrees-C. Using the concept of competing equilibria, we show that the equilibrium constant describing hydrogen bonding between the OH group of PVPh and the ether oxygen of PEO can be determined from quantitative infrared spectroscopic analysis of the fraction of hydrogen-bonded PVAc carbonyl groups in single-phase ternary compositions rich in PVPh.
引用
收藏
页码：7101 / 7106
页数：6
相关论文
共 50 条
[21]   Ionic Association in Hydrogen-Bonding Solvents [J].
Evans, D. Fennell ;
Matesich, Mary A. .
JOURNAL OF SOLUTION CHEMISTRY, 1973, 2 (2-3) :193-215
[22]   HYDROGEN-BONDING AND ASSOCIATION OF CERTAIN PHOSPHADEPSIPEPTIDES [J].
MATROSOV, EI ;
MASTRYUKOVA, TA ;
SHIPOV, AE ;
VAISBERG, MS ;
KABACHNIK, MI .
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1977, 26 (11) :2310-2314
[23]   THERMODYNAMICS OF HYDROGEN-BONDING IN POLYMER BLENDS .1. APPLICATION OF ASSOCIATION MODELS [J].
PAINTER, PC ;
PARK, Y ;
COLEMAN, MM .
MACROMOLECULES, 1989, 22 (02) :570-579
[24]   HYDROGEN-BONDING AND THE COLLAPSE OF SWOLLEN POLYMER GELS [J].
SHENOY, S ;
COLEMAN, M ;
PAINTER, P .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 203 :8-PMSE
[25]   A COMPARISON OF MODELS FOR HYDROGEN-BONDING IN POLYMER BLENDS [J].
PAINTER, PC ;
VEYTSMAN, B ;
COLEMAN, MM .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (06) :1189-1193
[26]   HYDROGEN-BONDING INTERACTION IN INTERPENETRATING POLYMER NETWORKS [J].
KIM, HI ;
KWEI, TK ;
PEARCE, EM .
CONTEMPORARY TOPICS IN POLYMER SCIENCE, VOL 6: MULTIPHASE MACROMOLECULAR SYSTEMS, 1989, 6 :687-697
[27]   HYDROGEN-BONDING INTERACTION IN INTERPENETRATING POLYMER NETWORK [J].
KIM, H ;
KWEI, TK ;
PEARCE, EM .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 :201-POLY
[28]   Multicomponent diffusion of hydrogen-bonding solutes in a polymer [J].
Elabd, YA ;
Barbari, TA .
AICHE JOURNAL, 2002, 48 (08) :1610-1620
[29]   Polymer Acceptor with Hydrogen-Bonding Functionality for Efficient and Mechanically Robust Ternary Organic Solar Cells [J].
Wan, Qingpei ;
Jeon, Hyerin ;
Seo, Soodeok ;
Oh, Eun Sung ;
Lee, Jin-Woo ;
Wang, Cheng ;
Kim, Taek-Soo ;
Kim, Bumjoon J. ;
Thompson, Barry C. .
CHEMISTRY OF MATERIALS, 2023, 35 (24) :10476-10486
[30]   Optimizing hydrogen-bonding in creating miscible liquid crystalline polymer blends by structural modification of the blend components [J].
Viswanathan, S ;
Dadmun, MD .
MACROMOLECULES, 2003, 36 (09) :3196-3205
12345