HYDROGEN-BONDING IN TERNARY POLYMER BLEND SYSTEMS - DETERMINATION OF ASSOCIATION PARAMETERS

被引：22
|
作者：
LEMENESTREL, C
BHAGWAGAR, DE
PAINTER, PC
COLEMAN, MM
GRAF, JF
机构：
[1] PENN STATE UNIV,DEPT MAT SCI & ENGN,UNIV PK,PA 16802
[2] GEC LTD,PARKERSBURG,WV 26181
来源：
MACROMOLECULES | 1992年 / 25卷 / 26期
关键词：
D O I：
10.1021/ma00052a005
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The polymer blend system consisting of poly(4-vinylphenol)(PVPh), poly(vinylacetate)(PVAc), and poly(ethylene oxide) (PEO) represents a rare case of a ternary system in which each binary pair is miscible in the amorphous state at 150-degrees-C. Using the concept of competing equilibria, we show that the equilibrium constant describing hydrogen bonding between the OH group of PVPh and the ether oxygen of PEO can be determined from quantitative infrared spectroscopic analysis of the fraction of hydrogen-bonded PVAc carbonyl groups in single-phase ternary compositions rich in PVPh.
引用
收藏
页码：7101 / 7106
页数：6
相关论文
共 50 条
  • [1] POLYMER BLEND COMPATIBILIZATION THROUGH HYDROGEN-BONDING
    KWEI, TK
    PEARCE, EM
    CHEN, JP
    MIN, BY
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 188 (AUG): : 145 - PMSE
  • [2] HYDROGEN-BONDING IN POLYMER SYSTEMS
    CANGELOSI, F
    SHAW, MT
    POLYMER ENGINEERING AND SCIENCE, 1983, 23 (12): : 669 - 675
  • [3] A thermodynamic approach to study hydrogen-bonding interactions in solvent/solvent/polymer ternary systems
    García-Lopera, Rosa
    Monzó, Isidro S.
    Abad, Concepción
    Campos, Agustín
    European Polymer Journal, 2007, 43 (01): : 231 - 242
  • [4] A thermodynamic approach to study hydrogen-bonding interactions in solvent/solvent/polymer ternary systems
    Garcia-Lopera, Rosa
    Monzo, Isidro S.
    Abad, Concepcion
    Campos, Agustin
    EUROPEAN POLYMER JOURNAL, 2007, 43 (01) : 231 - 242
  • [5] CHARACTERIZATION OF HYDROGEN-BONDING IN CELLULOSE SYNTHETIC-POLYMER BLEND SYSTEMS WITH REGIOSELECTIVELY SUBSTITUTED METHYLCELLULOSE
    KONDO, T
    SAWATARI, C
    MANLEY, RS
    GRAY, DG
    MACROMOLECULES, 1994, 27 (01) : 210 - 215
  • [6] CHARACTERIZATION OF HYDROGEN-BONDING IN CELLULOSE-SYNTHETIC POLYMER BLEND SYSTEMS WITH SPECIFICALLY SUBSTITUTED METHYLCELLULOSE
    KONDO, T
    SAWATARI, C
    MANLEY, RS
    GRAY, DG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 66 - CELL
  • [7] THE EFFECT OF HYDROGEN-BONDING ON THE PHASE-BEHAVIOR OF TERNARY POLYMER BLENDS
    ZHANG, HX
    BHAGWAGAR, DE
    GRAF, JF
    PAINTER, PC
    COLEMAN, MM
    POLYMER, 1994, 35 (25) : 5379 - 5397
  • [8] A Healable Supramolecular Polymer Blend Based on Aromatic π-π Stacking and Hydrogen-Bonding Interactions
    Burattini, Stefano
    Greenland, Barnaby W.
    Merino, Daniel Hermida
    Weng, Wengui
    Seppala, Jonathan
    Colquhoun, Howard M.
    Hayes, Wayne
    Mackay, Michael E.
    Hamley, Ian W.
    Rowan, Stuart J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (34) : 12051 - 12058
  • [9] Hydrogen-bonding in polymer blends
    Kuo, Shiao-Wei
    JOURNAL OF POLYMER RESEARCH, 2008, 15 (06) : 459 - 486
  • [10] HYDROGEN-BONDING IN POLYMER MIXTURES
    KWEI, TK
    PEARCE, EM
    REN, F
    CHEN, JP
    JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1986, 24 (07) : 1597 - 1609
12345