THE KINETICS OF THE REDUCTION OF METHYL VIOLOGEN AND 9,10-ANTHRAQUINONE-2-SULFONATE BY THE BENZOPINACOL ANION

被引:0
作者
BIGGER, SW [1 ]
CRAIG, RA [1 ]
GRIESER, F [1 ]
ROUCH, AJ [1 ]
SCHEIRS, J [1 ]
机构
[1] UNIV MELBOURNE,SCH CHEM,PARKVILLE,VIC 3052,AUSTRALIA
关键词
D O I
10.1002/kin.550240802
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reduction of methyl viologen (MV2+) and 9,10-anthraquinone-2-sulfonate (AQS) by the benzopinacol anion in 50% (v/v) propan-2-ol/water was investigated spectroscopically. The rate constants for these reactions were found to be 12.9 +/- 0.2 and 0.23 +/- 0.01 M-1 s-1, respectively.
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页码:689 / 693
页数:5
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