FORMATION OF MOLYBDENUM-ETA-4-TRIMETHYLENEMETHANE CATIONS THROUGH CARBON CARBON BOND FORMATION

被引：14

作者：

SU, GM

LEE, GH

PENG, SM

LIU, RS

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM,TAIPEI 10764,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of BF3.Et2O, the molybdenum-eta-3-allyl complex [Mo(eta-5-C5H5)(CO)2{eta-3-anti-1-Me, 2-(CH2 = CPh)C3H3}] reacts with benzaldehyde, methyl vinyl ketone and acetone to give the corresponding eta-4-trimethylenemethane cations; the crystal structure of a pyran complex generated from such cations and of a related complex are reported.

引用

收藏

页码：215 / 217

页数：3

相关论文

共 15 条

[1] REACTIONS OF COORDINATED LIGANDS .30. THE TRANSFORMATION OF METHYLENECYCLOPROPANES INTO CATIONIC "ETA-4-TRIMETHYLENEMETHANEMOLYBDENUM COMPLEXES, REACTIONS WITH NUCLEOPHILIC-REAGENTS, AND THE MOLECULAR-STRUCTURE OF [MO(ETA-4-C(CH2)3)(CO)2(ETA-C5ME5)][BF4] [J].

ALLEN, SR ;

BARNES, SG ;

GREEN, M ;

MORAN, G ;

TROLLOPE, L ;

MURRALL, NW ;

WELCH, AJ ;

SHARAIHA, DM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (06) :1157-1169

[2] INTRAMOLECULAR CYCLIZATION OF CATIONIC ETA-4-DIENE COMPLEXES OF MOLYBDENUM - A NEW SYNTHESIS OF TETRAHYDROFURANS, TETRAHYDROPYRANS, AND CYCLOPENTANES [J].

BAXTER, JS ;

GREEN, M ;

LEE, TV .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (21) :1595-1596

[3] TRIMETHYLENEMETHANEIRON TRICARBONYL COMPLEXES [J].

EHRLICH, K ;

EMERSON, GF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (07) :2464-&

[4] FUNCTIONALIZATION OF 1,3-DIENES USING CATIONIC COMPLEXES OF MOLYBDENUM [J].

GREEN, M ;

GREENFIELD, S ;

KERSTING, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (01) :18-20

[5] PALLADIUM(II)-ASSISTED REACTIONS OF MONOOLEFINS [J].

HEGEDUS, LS .

TETRAHEDRON, 1984, 40 (13) :2415-2434

[6] TRIMETHYLENEMETHANE METAL-COMPLEXES .1. SYNTHESIS OF RUTHENIUM, OSMIUM, RHODIUM, AND IRIDIUM COMPLEXES [J].

JONES, MD ;

KEMMITT, RDW ;

PLATT, AWG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (07) :1411-1418

[7]

PEARSON AJ, 1990, SYNLETT, P10

[8] NATURAL-PRODUCTS SYNTHESIS USING ORGANOIRON COMPLEXES [J].

PEARSON, AJ .

PURE AND APPLIED CHEMISTRY, 1983, 55 (11) :1767-1779

[9]

PETTIT R, 1970, J CHEM SOC CHEM COMM, P1419

[10] NUCLEOPHILIC-ADDITION TO DIENE AND ARENE-METAL COMPLEXES [J].

SEMMELHACK, MF .

PURE AND APPLIED CHEMISTRY, 1981, 53 (12) :2379-2388