(NBU4P)2[OS20(CO)40], A THERMOLYTICALLY GENERATED HIGH-NUCLEARITY CLUSTER WITH A TETRAHEDRAL CUBIC-CLOSE-PACKED METAL CORE

被引：43

作者：

AMOROSO, AJ

GADE, LH

JOHNSON, BFG

LEWIS, J

RAITHBY, PR

WONG, WT

机构：

[1] University Chemical Laboratory, Cambridge, CB2 1EW, Lensfield Road

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199101071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fully symmetrical osmium tetrahedron consisting of twenty cubic-close-packed metal atoms constitutes the framework of dianion 1. There is no evidence for interstitial carbon or hydrogen atoms in the framework. Moreover, the Os-Os distances approach those of elemental osmium. Cyclovoltammetric measurements indicate that 1 exhibits interesting electrochemical properties (see also the Highlight on p. 72).

引用

页码：107 / 109

页数：3

共 7 条

[1] [(PH3P)2N]2[OS18HG2C2(CO)42] A PHOTOCHEMICALLY GENERATED HIGH-NUCLEARITY CLUSTER WHICH REVERSIBLY INCORPORATES METALLIC MERCURY INTO ITS METAL CORE
CHARALAMBOUS, E
GADE, LH
JOHNSON, BFG
KOTCH, T
LEES, AJ
LEWIS, J
MCPARTLIN, M
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (10): : 1137 - 1139
[2] UNSATURATION IN A HIGH-NUCLEARITY METAL-CARBONYL CLUSTER COMPLEX - SYNTHESIS, STRUCTURES, AND INTERCONVERSIONS OF PT2OS4(CO)12(COD)2 AND PT2OS4(CO)11(COD)2
ADAMS, RD
WU, WG
ORGANOMETALLICS, 1991, 10 (01) : 35 - 36
[3] First-known high-nuclearity silver-nickel carbonyl cluster:: nanosized [Ag16Ni24(CO)40]4- possessing a new 40-atom cubic Td closed-packed metal-core geometry
Zhang, JM
Dahl, LF
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (07): : 1269 - 1274
[4] CLUSTER SYNTHESIS .4. THE ROLE OF SULFIDO LIGANDS IN THE SYNTHESIS OF HIGH NUCLEARITY METAL-CARBONYL CLUSTER COMPOUNDS - THE SYNTHESIS OF OS4(CO)13(MU-3-S)2 AND OS7(CO)20(MU-4-S)2 AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF OS7(CO)20(MU-4-S)2
ADAMS, RD
HORVATH, IT
MATHUR, P
SEGMULLER, BE
YANG, LW
ORGANOMETALLICS, 1983, 2 (09) : 1078 - 1083
[5] A high-nuclearity Ni-Sb carbonyl cluster displaying unprecedented metal stereochemistries:: synthesis and X-ray structure of [NEt4]6[Ni31Sb4(CO)40]•2 Me2CO
Femoni, C
Iapalucci, MC
Longoni, G
Svensson, PH
CHEMICAL COMMUNICATIONS, 2000, (08) : 655 - 656
[6] SYNTHESIS AND CHARACTERIZATION OF A NEW BINARY DECA-OSMIUM CARBONYL CLUSTER ANION - AN INTERMEDIATE IN THE FORMATION OF OTHER HIGH-NUCLEARITY OSMIUM CARBONYL CLUSTERS - CRYSTAL AND MOLECULAR-STRUCTURE OF (PH4P)2[OS10(CO)26]
AMOROSO, AJ
JOHNSON, BFG
LEWIS, J
RAITHBY, PR
WONG, WT
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (11): : 1505 - 1506
[7] SYNTHESIS AND EXPERIMENTAL THEORETICAL INVESTIGATION OF THE HIGH-NUCLEARITY CUBIC T-D[AU6NI12(CO)(24)](2-) CLUSTER, AN INITIAL EXAMPLE OF A DISCRETE GOLD NICKEL BIMETALLIC-BONDED SPECIES - COMPARATIVE-ANALYSIS OF THE RESULTS OF ELECTRON-COUNTING METHODS AND THE FENSKE-HALL MO MODEL IN RATIONALIZING THE BONDING INTERACTIONS OF ITS AU6NI12 CORE CONSISTING OF 5 FACE-FUSED METAL OCTAHEDRA
JOHNSON, AJW
SPENCER, B
DAHL, LF
INORGANICA CHIMICA ACTA, 1994, 227 (02) : 269 - 283

← 1 →