Hydrolysis preparation of the compact TiO2 layer using metastable TiCl4 isopropanol/water solution for inorganic-organic hybrid heterojunction perovskite solar cells

被引:12
作者
Dai Xiaoyan [1 ,2 ]
Shi Chengwu [1 ,2 ]
Zhang Yanru [1 ,2 ]
Wu Ni [1 ,2 ]
机构
[1] Hefei Univ Technol, Sch Chem & Chem Engn, Hefei 230009, Anhui, Peoples R China
[2] Chinese Acad Sci, Key Lab Novel Thin Film Solar Cells, Hefei 230031, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
compact TiO2 layer; TiCl4; hydrolysis; thin films; perovskite solar cell;
D O I
10.1088/1674-4926/36/7/074003
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A hydrolysis process was applied to prepare the compact TiO2 layer using the fresh metastable TiCl4 isopropanol/water solution as the precursor solution for the preparation of the inorganic-organic hybrid heterojunction perovskite solar cells. The optimal compact TiO2 layer prepared from the aqueous solution of 2 mol/L TiCl4 diluted in isopropanol at 1 : 3 by volume as precursor solution was uniform and with a film thickness of 126 nm. The corresponding perovskite solar cell gave a photovoltaic conversion efficiency of 10.61%.
引用
收藏
页数:4
相关论文
共 15 条
[1]   Low-temperature processed meso-superstructured to thin-film perovskite solar cells [J].
Ball, James M. ;
Lee, Michael M. ;
Hey, Andrew ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1739-1743
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process [J].
Chen, Qi ;
Zhou, Huanping ;
Hong, Ziruo ;
Luo, Song ;
Duan, Hsin-Sheng ;
Wang, Hsin-Hua ;
Liu, Yongsheng ;
Li, Gang ;
Yang, Yang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :622-625
[4]   Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates [J].
Docampo, Pablo ;
Ball, James M. ;
Darwich, Mariam ;
Eperon, Giles E. ;
Snaith, Henry J. .
NATURE COMMUNICATIONS, 2013, 4
[5]   Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells [J].
Eperon, Giles E. ;
Stranks, Samuel D. ;
Menelaou, Christopher ;
Johnston, Michael B. ;
Herz, Laura M. ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (03) :982-988
[6]   Structural transformation of nanocrystalline titania grown by sol-gel technique and the growth kinetics of crystallites [J].
Hu, LH ;
Dai, SY ;
Wang, KJ .
ACTA PHYSICA SINICA, 2003, 52 (09) :2135-2139
[7]   Efficient Inorganic Organic Hybrid Perovskite Solar Cells Based on Pyrene Arylamine Derivatives as Hole-Transporting Materials [J].
Jeon, Nam Joong ;
Lee, Jaemin ;
Noh, Jun Hong ;
Nazeeruddin, Mohammad Khaja ;
Graetzel, Michael ;
Seok, Sang Il .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (51) :19087-19090
[8]   Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites [J].
Lee, Michael M. ;
Teuscher, Joel ;
Miyasaka, Tsutomu ;
Murakami, Takurou N. ;
Snaith, Henry J. .
SCIENCE, 2012, 338 (6107) :643-647
[9]   A hole-conductor-free, fully printable mesoscopic perovskite solar cell with high stability [J].
Mei, Anyi ;
Li, Xiong ;
Liu, Linfeng ;
Ku, Zhiliang ;
Liu, Tongfa ;
Rong, Yaoguang ;
Xu, Mi ;
Hu, Min ;
Chen, Jiangzhao ;
Yang, Ying ;
Graetzel, Michael ;
Han, Hongwei .
SCIENCE, 2014, 345 (6194) :295-298
[10]   Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells [J].
Nazeeruddin, MK ;
Péchy, P ;
Renouard, T ;
Zakeeruddin, SM ;
Humphry-Baker, R ;
Comte, P ;
Liska, P ;
Cevey, L ;
Costa, E ;
Shklover, V ;
Spiccia, L ;
Deacon, GB ;
Bignozzi, CA ;
Grätzel, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (08) :1613-1624