BONDING STATE OF FLUORINE IN LEAD TIN OXYFLUOROPHOSPHATE GLASSES

被引：34

作者：

OSAKA, A ^{[1
]}

MIURA, Y ^{[1
]}

TSUGARU, T ^{[1
]}

机构：

[1] KURARAY CO LTD,CENT LABS,SAKAZU,KURASHIKI 710,JAPAN

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1990年 / 125卷 / 1-2期

关键词：

D O I：

10.1016/0022-3093(90)90326-H

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

X-ray photoelectron spectra (XPS) and infrared spectra were measured for lead-tin oxyfluorophosphate glasses and the bonding state of fluorine atoms was investigated. F 1s XPS had a doublet peak: one of the component peaks at 687.4 eV in binding energy was attributed to the fluorine in PF bonds, and the other at 684.9 eV to the fluorine in ionic MF bonds (M:Pb(II) and Sn(II)). The fraction of the latter increases with increase in the fluorine content. © 1990.

引用

页码：87 / 92

页数：6

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